So if I try to rotate my 2 atoms, you see that I have to break that pi bond, because they need to be lined up so that the electron density can overlap.

如果我要试着转动两个原子，你会看到我必须要打破一个π键，因为他们需要连接起来,让那些电子能够重叠。

麻省理工公开课 - 化学原理课程节选

This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.

这应该是合理的,因为如果某物的电离能很低，这也就意味着它的电负性也不高，那么它就会更愿意,放弃一定的电子密度，而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。

麻省理工公开课 - 化学原理课程节选

So if we write out every term individually, what we end up with is essentially just the probability density for the first atom, then the probability density for the second atom, and then we have this last term here, and this is what ends up being the interference term.

如果我们把每一项都写出来，最后得到的就是,第一个原子的概率密度，然后是第二个原子的概率密度，然后是这最后一项，这就是干涉项。

麻省理工公开课 - 化学原理课程节选

Then we go negative and we go through zero again, which correlates to the second area of zero, that shows up also in our probability density plot, and then we're positive again 0 and approach zero as we go to infinity for r.

并且再次经过,这和，第二块等于0的区域相关联,这也在,我们的概率密度图里反映出来了，然后它又成了正的,并且当r趋于无穷时它趋于。

麻省理工公开课 - 化学原理课程节选