It can be spelled y-o-g-u-r-t or y-o-g-h-u-r-t.
VOA: special.2009.01.19
Now, before, of course, in the first part of the class u we started out looking at u H and then looking at H not as functions of S and V or S and p, but as functions of temperature, mostly.
现在,在本课的前一部分,我们首先讨论了,然后讨论了,这两个量并未写成S和V或者S和p的函数,而是写成了温度的函数。
And now we're almost done, except what we H really want is delta H and not delta U, right.
我们差不多已经完成了,除了我们实际上想要的是Δ
The agreement to be signed Thursday replaces the START-1 treaty, which U.S.President George H.W.Bush and Soviet President Mikhail Gorbachev signed in 1991.
VOA: standard.2010.04.04
And the bigger lesson from that is that entropy, unlike energy u or enthalpy H, we could define an absolutely number for it.
热力学第三定律的一个更重要的推论是,与内能和自由焓不同,我们可以给上定义一个绝对的数值。
H.K.Suh from the group Korean Americans for Peace said he believes a drawdown of U.S.troops everywhere, including on the dividing line between the two Koreas, would be beneficial to the United States.
VOA: standard.2010.03.20
Now, you know with constant volume, H now it's not going to be delta H that's U straightforward to measure, it's going to be dealt u, all right.
好,现在你们知道在体积恒定的条件下,我们得到的不是Δ,我们直接测量到的是Δ,好,但这基本上也是一样的。
Delta u, delta H, familiar state functions, q w changes in their values, q, w, heat and work.
U,△H,很熟悉的态函数,它们的值在变化;
So, I just want to write a few examples down with a few values for delta u or delta H or delta S, and see whether we can get any clues from what we see.
我先写一些例子,例子包含一些内能,自由焓和熵的变化数值,然后看从中,我们能不能得到一些启示。
Do we calculate, you know, delta S, delta u, delta H?
是否要计算熵的变化,内能的变化,自由焓的变化?
And that in the case of constant volume, U in this case that's my delta u, and then I'll H add my little delta n term to get delta H.
这是在等体情形下,此时的到的是Δ,然后我可以加上Δn的项来得到Δ
OK, delta H is delta of u plus pV. By definition that's how we define enthalpy up here.
好,ΔH=Δ,根据定义,这就是我们。
Where the Gibbs free energy, TS u plus pV minus TS is H minus TS.
吉布斯自由能等于,内能u加上pV减去TS,也是自由焓H减去。
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
H Now, let's go back to our older friends u and H.
回到我们的老朋友u和。
So here are results for pathway A, right, for delta u zero delta H zero. I didn't actually explicitly write it or did I?
这是路径A的结果,△U是零,△H是零,我没有明确地写出来,是吧?让我们把它再写一遍?
H=qp The u plus p V. Delta H is equal to q V.
括号里面的就是H,等于u+pv,Δ
pV So our H is u plus pV, as you know.
我们的自由焓H等于内能u加上。
Let's look at those quantities. u and H.
然后看u和H这两个物理量。
du But here you've got pressure constant. du, T this is du, not H here. du/dT is only equal Cv to Cv when the volume is constant, not when the pressure is constant.
这里是压强横笛,du,这是,不是H,偏U偏,只在体积恒定时等于,而不是压强恒定时。
And it's more dramatic if the system is a gas p T2 V2 p, T2, V2, And let's look at what happens to U these functions of state, to H to u under this transformation.
如果是气体这个系统,就更具有趣了,让我们看看H和,在这个变化中态函数会发生什么变化。
In some sense, that's one reason to associate this as a kind of energy, H just like mechanical energy u or enthalpy H, it's the minimum free energy state that is the equilibrium state under the relevant conditions.
在某种意义下,这是我们把这些物理量称为能量的原因,就像机械能U和自由焓,具有最小自由能的状态在特定的条件下,就是平衡态。
应用推荐