• It can be spelled y-o-g-u-r-t or y-o-g-h-u-r-t.

    VOA: special.2009.01.19

  • Now, before, of course, in the first part of the class u we started out looking at u H and then looking at H not as functions of S and V or S and p, but as functions of temperature, mostly.

    现在,在本课的前一部分,我们首先讨论了,然后讨论了,这两个量并未写成S和V或者S和p的函数,而是写成了温度的函数。

    麻省理工公开课 - 热力学与动力学课程节选

  • And now we're almost done, except what we H really want is delta H and not delta U, right.

    我们差不多已经完成了,除了我们实际上想要的是Δ

    麻省理工公开课 - 热力学与动力学课程节选

  • The agreement to be signed Thursday replaces the START-1 treaty, which U.S.President George H.W.Bush and Soviet President Mikhail Gorbachev signed in 1991.

    VOA: standard.2010.04.04

  • And the bigger lesson from that is that entropy, unlike energy u or enthalpy H, we could define an absolutely number for it.

    热力学第三定律的一个更重要的推论是,与内能和自由焓不同,我们可以给上定义一个绝对的数值。

    麻省理工公开课 - 热力学与动力学课程节选

  • H.K.Suh from the group Korean Americans for Peace said he believes a drawdown of U.S.troops everywhere, including on the dividing line between the two Koreas, would be beneficial to the United States.

    VOA: standard.2010.03.20

  • Now, you know with constant volume, H now it's not going to be delta H that's U straightforward to measure, it's going to be dealt u, all right.

    好,现在你们知道在体积恒定的条件下,我们得到的不是Δ,我们直接测量到的是Δ,好,但这基本上也是一样的。

    麻省理工公开课 - 热力学与动力学课程节选

  • Delta u, delta H, familiar state functions, q w changes in their values, q, w, heat and work.

    U,△H,很熟悉的态函数,它们的值在变化;

    麻省理工公开课 - 热力学与动力学课程节选

  • So, I just want to write a few examples down with a few values for delta u or delta H or delta S, and see whether we can get any clues from what we see.

    我先写一些例子,例子包含一些内能,自由焓和熵的变化数值,然后看从中,我们能不能得到一些启示。

    麻省理工公开课 - 热力学与动力学课程节选

  • Do we calculate, you know, delta S, delta u, delta H?

    是否要计算熵的变化,内能的变化,自由焓的变化?

    麻省理工公开课 - 热力学与动力学课程节选

  • And that in the case of constant volume, U in this case that's my delta u, and then I'll H add my little delta n term to get delta H.

    这是在等体情形下,此时的到的是Δ,然后我可以加上Δn的项来得到Δ

    麻省理工公开课 - 热力学与动力学课程节选

  • OK, delta H is delta of u plus pV. By definition that's how we define enthalpy up here.

    好,ΔH=Δ,根据定义,这就是我们。

    麻省理工公开课 - 热力学与动力学课程节选

  • Where the Gibbs free energy, TS u plus pV minus TS is H minus TS.

    吉布斯自由能等于,内能u加上pV减去TS,也是自由焓H减去。

    麻省理工公开课 - 热力学与动力学课程节选

  • Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.

    因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。

    麻省理工公开课 - 热力学与动力学课程节选

  • H Now, let's go back to our older friends u and H.

    回到我们的老朋友u和。

    麻省理工公开课 - 热力学与动力学课程节选

  • So here are results for pathway A, right, for delta u zero delta H zero. I didn't actually explicitly write it or did I?

    这是路径A的结果,△U是零,△H是零,我没有明确地写出来,是吧?让我们把它再写一遍?

    麻省理工公开课 - 热力学与动力学课程节选

  • H=qp The u plus p V. Delta H is equal to q V.

    括号里面的就是H,等于u+pv,Δ

    麻省理工公开课 - 热力学与动力学课程节选

  • pV So our H is u plus pV, as you know.

    我们的自由焓H等于内能u加上。

    麻省理工公开课 - 热力学与动力学课程节选

  • Let's look at those quantities. u and H.

    然后看uH这两个物理量。

    麻省理工公开课 - 热力学与动力学课程节选

  • du But here you've got pressure constant. du, T this is du, not H here. du/dT is only equal Cv to Cv when the volume is constant, not when the pressure is constant.

    这里是压强横笛,du,这是,不是H,偏U偏,只在体积恒定时等于,而不是压强恒定时。

    麻省理工公开课 - 热力学与动力学课程节选

  • And it's more dramatic if the system is a gas p T2 V2 p, T2, V2, And let's look at what happens to U these functions of state, to H to u under this transformation.

    如果是气体这个系统,就更具有趣了,让我们看看H和,在这个变化中态函数会发生什么变化。

    麻省理工公开课 - 热力学与动力学课程节选

  • In some sense, that's one reason to associate this as a kind of energy, H just like mechanical energy u or enthalpy H, it's the minimum free energy state that is the equilibrium state under the relevant conditions.

    在某种意义下,这是我们把这些物理量称为能量的原因,就像机械能U和自由焓,具有最小自由能的状态在特定的条件下,就是平衡态。

    麻省理工公开课 - 热力学与动力学课程节选

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