• After a bullish start this year, a wave of pessimism appears to be taking root.

    VOA: standard.2010.05.25

  • And now that we do have something, namely, this wave of colonization, they join that as well.

    这与我们找到的证据相符,这些人加入了殖民的浪潮

    耶鲁公开课 - 古希腊历史简介课程节选

  • So, now I hope you have in your mind a picture of the way the Greek world had expanded by the time this wave of colonization was complete--pretty complete, sometime in the seventh century B.C.

    希望现在你脑海中有一幅,那时候希腊世界扩张的地图,在公元前七世纪的某一阶段,形成了一个完整的殖民浪潮,相当完整

    耶鲁公开课 - 古希腊历史简介课程节选

  • Losing that seat in the Senate has hurt their chances of passing sweeping health care reform and unleashed a wave of anxiety ahead of congressional elections this November.

    VOA: standard.2010.01.28

  • So we have the operationon the wave function in terms of r, theta, and phi and remember this e is just our binding energy for the electron, and we get back out this wave function.

    我们用r,θ,φ来表示,将算符作用于波函数,而且记住e仅仅是电子结合能,然后后面加上波函数。

    麻省理工公开课 - 化学原理课程节选

  • Well, if this thing is going to vibrate for any length of time it better be a standing wave.

    好的,如果它在任意时间振动,那它就是驻波。

    麻省理工公开课 - 固态化学导论课程节选

  • So I'm going to wave my hands at what one fflush of these things here does, fflush here, but I decided this is kind of a weak implementation.

    所以我将向这些东西所做的挥手,这里的,但是我觉得这是个有点无力的实现。

    哈佛公开课 - 计算机科学课程节选

  • But he could only wave his hands as to how this physical thing in the world could connect to an immaterial mind.

    但他只能用挥手这样的动作,来展示现实的生理客体,是如何与无形心理相联系的

    耶鲁公开课 - 心理学导论课程节选

  • The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.

    我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候,如果你们看,波函数,的角向部分,你们会发现它是一个常数。

    麻省理工公开课 - 化学原理课程节选

  • Our friend Schr?dinger told us that if you solve for the wave function, this is what the probability densities look like.

    我们的朋友薛定谔告诉我们,如果你用波函数来解决,你就会知道这些概率密度看上去的样子。

    麻省理工公开课 - 固态化学导论课程节选

  • And if it is going to be a standing wave then this must be an integral number of wavelengths.

    如果这有个驻波的话,那么周长就是个整数。

    麻省理工公开课 - 固态化学导论课程节选

  • So this validates de Broglie and it also validates the whole concept of wave-particle duality.

    这就证实了德布罗意的观点,也证实了,波粒二象性的原理。

    麻省理工公开课 - 固态化学导论课程节选

  • And the person we have to thank for actually giving us this more concrete way to think about what a wave function squared is is Max Born here.

    需要感谢,马克思,波恩,给了我们,这个波函数平方的,具体解释,事实上。

    麻省理工公开课 - 化学原理课程节选

  • Remember this is our bond axis here, and you can see there is this area where the wave function is equal to zero all along that plane, that's a nodal plane.

    记住这是我们的键轴,你可以看到在这些区域,波函数在这个面内全都是零,这是节点面。

    麻省理工公开课 - 化学原理课程节选

  • So, we're talking about wave functions and we know that means orbitals, but this is -- probably the better way to think about is the physical interpretation of the wave function.

    我们讨论波函数而且,我们知道它代表着轨道,但-也许更好的思考方法是,考虑波函数的物理意义。

    麻省理工公开课 - 化学原理课程节选

  • We can't actually go ahead and derive this equation of the wave function squared, because no one ever derived it, it's just an interpretation, but it's an interpretation that works essentially perfectly.

    从这个方程中,导出,波函数的平方,没有人可以这样做,这仅仅是一种解释,但这种解释,能解释的很好,自从它第一次被提出来之后。

    麻省理工公开课 - 化学原理课程节选

  • In order to have an electron in a stationary orbit this implies standing wave.

    为了在静止的轨道中拥有电子,驻波是不可少的。

    麻省理工公开课 - 固态化学导论课程节选

  • Again we can look at this in terms of thinking about a picture this way, in terms of drawing the wave function out on an axis.

    同样我们可以,用这个图像来考虑,从画轴上的波函数来考虑。

    麻省理工公开课 - 化学原理课程节选

  • But before we get to that, in terms of thinking just think, OK, this is representing my particle, this is representing my electron that's what the wave function is.

    但是在我们谈论那个部分之前,在理解方面,仅仅是理解,好的,它代表了粒子,它代表了电子,这就是波函数。

    麻省理工公开课 - 化学原理课程节选

  • I want to get to this same place now by wave mechanics.

    我想用波动力学,来得到这些。

    麻省理工公开课 - 固态化学导论课程节选

  • This is a table that's directly from your book, and what it's just showing is the wave function for a bunch of different orbitals.

    这是一张你们书里的表格,它展示了各种,不同的轨道波函数。

    麻省理工公开课 - 化学原理课程节选

  • So, at this place where it hits zero, 0 that means that the square of the wave function is also going to be zero, right.

    它达到0的地方,这意味着波函数的,平方也是,如果我们看概率密度图。

    麻省理工公开课 - 化学原理课程节选

  • So, the wave function at all of these points in this plane is equal to zero, so therefore, also the wave function squared is going to be equal to zero.

    因此这里的,波函数平方也等于零,如果我们说在这整个平面上,任何地方找到一个p电子的概率都是零。

    麻省理工公开课 - 化学原理课程节选

  • But luckily we don't have to worry about how we're going to picture all this, now that I said that, no physical interpretation f or a wave function, there is a physical interpretation for what a wave function squared means.

    如何想象这些图像,我这么说,虽然波函数,物理解释,但波函数的平方,有物理解释,当我们说到。

    麻省理工公开课 - 化学原理课程节选

  • So this is our complete description of the ground state wave function.

    所以这是我们,对基态波函数的完整描述。

    麻省理工公开课 - 化学原理课程节选

  • So, remember this makes sense if you just think of it as a wave and forget the particle part of it for right now, because that would be very upsetting to think about and that's not, in fact, what's going on, we're talking about quantum mechanics here.

    记住如果你们把它看做是一个波,而忘记它是一个粒子时,这就是可以理解的了,因为如果把它看做,一个粒子就行不通了,实际上也不是这样的,这里我们是以量子力学的角度来考虑问题。

    麻省理工公开课 - 化学原理课程节选

  • So this symbol here is actually what we call a wave function.

    这里的这个符号,实际上是一个波函数。

    麻省理工公开课 - 化学原理课程节选

  • So now that we can do this, we can compare and think about, we know how to consider wave functions for individual electrons in multi-electron atoms using those Hartree orbitals or the one electron wave approximations.

    现在我们可以做这些了,我们可以对比和考虑,我们知道如何用哈特里轨道,或者单电子波近似去考虑,多电子原子中的单个电子波函数,所以对于我们研究了。

    麻省理工公开课 - 化学原理课程节选

  • The reason that we can talk about this is remember that we're talking about wave functions, we're talking about waves, so we can have constructive interference in which two different orbitals can constructively interfere, we can also have destructive interference.

    我们可以这么说的原因是,记住我们说的是波函数,我们说的是波函数,所以我们可以得到相长干涉,这是两个不同轨道会相长干涉,我们也有相消干涉。

    麻省理工公开课 - 化学原理课程节选

  • So, what this means is that when we're looking at an actual wave function, we're treating it as a wave, right, so waves can have both magnitude, but they can also have a direction, so they can be either positive or negative.

    这意味着,当我们看一个波函数时,我们把它看做一个波,波不仅有幅值,还有方向,所以它们可正可负,如果。

    麻省理工公开课 - 化学原理课程节选

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