• So this is a case where we have resonance structures, or we call this a resonance hybrid.

    因此在这种情况下我们就有了共振结构,或者我们叫它共振杂化。

    麻省理工公开课 - 化学原理课程节选

  • So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.

    如果我们考虑碳原子的形状,它是平面三角形,键角是,因为我们有这三个杂化轨道。

    麻省理工公开课 - 化学原理课程节选

  • I have four bonds that are of equal energy, and he called this an sp3 hybrid.

    我已经将4个能量相等的键画好了,他把这称为sp3杂化。

    麻省理工公开课 - 固态化学导论课程节选

  • So if you picture this as our s p 2 carbon atom where we have three hybrid orbitals, and then one p y orbital coming right out at us.

    如果你把这想象成sp2碳原子,这里有3个杂化轨道,然后一个py轨道朝向我们。

    麻省理工公开课 - 化学原理课程节选

  • So this is a little bit trickier to look at and see what it means, but essentially we have two hybrid orbitals, which are shown in blue here, and then we have one p orbital that's left alone that's going up and down on the page.

    看这个图肯能会觉得比较诡异,但本质上,骂我们有两个杂化轨道,这里用蓝色表示,还有剩下一个p轨道,在图中上下方向上。

    麻省理工公开课 - 化学原理课程节选

  • All right, so in terms of s p 3 hybrid orbitals, let's combine all four together on one axis, because this is what's going to happen in an s p 3 carbon atom.

    对于sp3杂化轨道,让我们把4个结合起来,因为这是sp3碳原子中发生的情况。

    麻省理工公开课 - 化学原理课程节选

  • sigma So we'll call this sigma, and it's between two s p 2 hybrid carbon atoms.

    我们可以叫它,它在两个sp2杂化碳原子之间。

    麻省理工公开课 - 化学原理课程节选

  • So, this forms a tetrahedron, which forms the sp3 hybrid orbitals.

    这就形成了一个四面体,它是由sp3杂化轨道形成的。

    麻省理工公开课 - 固态化学导论课程节选

  • So, if we think about this z bonding axis between the two carbon atoms, we can picture overlap of those s p hybrid orbitals, and then we can also picture bonding to hydrogen.

    如果我们考虑,两个碳原子之间的z成键轴,我们可以画出sp杂化轨道的交叠,我们也可以画出和氢原子的成键。

    麻省理工公开课 - 化学原理课程节选

  • And again, this is between the p orbitals, these are not hybrid orbitals, so when we name this bond we're going to name it as a pi bond here, because it's between two p orbitals, and it's going to be between the carbon 2 p y orbital, and the other carbon 2 p y orbital.

    同样,这是在p轨道之间的,它们不是杂化轨道,所以当我们命名这个键时,我们要命名它为π键,因为它在两个p轨道之间,而且是在碳2py轨道,和另一个碳2py轨道之间。

    麻省理工公开课 - 化学原理课程节选

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