Now, we saw before, or really I should say we accepted before, that for an ideal gas, u was a function of temperature only.
我们已经看到,或者说我们已经接受这样一个事实,即理想气体的内能只和温度有关。
In other words, now I know how to tell how the Helmholtz free energy changes as a function of temperature.
换句话说,我现在知道如何写出亥姆赫兹,自由能作为温度的函数。
H for an ideal gas is only a function of temperature. This is not true for a real gas fortunately, but it's true for an ideal gas.
不正确的,但是幸运的是,对于理想气体是完全正确的。
It's a state function, so we're at constant temperature and pressure, and now we want to consider some chemical change or a phase transition or you name it.
这就是态函数,我们处于恒定的温度和压强之下,然后考虑某些化学变化或者相变,或者你想考虑的东西。
You know, we've done a bunch of thermochemistry, and we've kind of seen that the energy of mixing, your energetics don't change too much as a function of temperature.
我们做过很多的化学热力学习题,某种程度上我们发现混合的能量,并不随着能量,发生大的改变。
So that you could see that for the ideal gas, u would not be a function of volume, but only of temperature.
所以我们可以看到对理想气体,内能不依赖于体积,而仅仅是温度的函数。
OK, now, we're going to look at the internal energy, and we're going to pretend that it is explicitly a function of temperature and volume.
好,我们接下来看看内能,我们假设,它是温度和体积的函数。
So for an ideal gas, we saw that u was only a function of temperature.
对于理想气体,我们知道内能只是温度的函数。
But it's allowed to say the internal energy is a function of temperature and volume.
但是我们也可以说内能,是温度和体积的函数。
Similarly for G as a function of temperature and pressure, I can go through the same procedure.
同样的G作为,温度和压强的函数,我可以采用相同的步骤。
That u is a function of temperature only.
内能只是温度的函数。
It's the function of temperature, as B.
它是温度的函数。
Cv So, for Cp and Cv, these are often quantities that are measured as a function of temperature, and one could, in fact, calculate this integral.
一般Cp和,都是温度的函数,因此实际上,我们可以将这个积分计算出来。
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
What is dH/dT as a function, keeping pressure constant, what is dH/dp, keeping temperature constant?
恒定时偏H偏T是什么,温度恒定时的偏H偏p又是什么呢?,好的,让我们解决第一个问题?
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