Because if it's irreversible, it's very likely that I don't know what the pressure inside the system is doing while this is happening.
因为对不可逆过程,系统内部的压强,没有明确的定义,气体不处于平衡态。
So for an irreversible process, I wouldn't really be allowed to put a path there.
不可逆过程,是无法画出路径曲线来的。
if it's a reversible process then the equality holds, but if it's irreversible, which means it happens spontaneously, T then dS is greater than this.
对于可逆过程,等号成立,但是如果是不可逆过程,这些不可逆过程是自发进行的,那么dS大于dq除以。
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