du If you measure something else, you won't get du.
如果你测量其它量,得到的就不是。
I was just yesterday-- I gave a talk in Montreal at the Caisse de Dep?t,et Placement du Quebec, which is the big wealth management fund for the Province of Quebec.
昨天,我刚在蒙特利的魁北克储蓄投资集团,做了一个讲演,这个投资集团是魁北克省的,一所大型财产管理基金机构。
du/dT And we discover that du/dT at constant V T is equal to du/dT at constant V.
可以发现恒定体积下的,等于恒定体积下的偏u偏。
du external dV minus T surroundings dS is less than zero.
加上压强p,du,plus,p,乘以dV减去环境温度T乘以dS小于零。
du/dV So now our du/dV, dp/dT at constant T is just T times dp/dT which is just p over T minus p, it's zero.
现在我们的恒定温度下的,等于T乘以dp/dT,在这里,等于p除以T,最后再减去p,结果是0。
So we have dH/dT keeping pressure constant, is du/dT keeping pressure constant.
等于偏U偏T,p恒定加上,偏pv偏T,p恒定。
pdV So, du is T dS minus p dV.
即du等于TdS减去。
du/dV at constant T. And so, what is it?
求恒定温度下的du/dV,但是,这个量是什么?
That's where that term comes from, du/dV dV/dT.
乘以偏V偏T,p恒定,这项的来源。
du But here you've got pressure constant. du, T this is du, not H here. du/dT is only equal Cv to Cv when the volume is constant, not when the pressure is constant.
这里是压强横笛,du,这是,不是H,偏U偏,只在体积恒定时等于,而不是压强恒定时。
OK, so for a constant volume process, du we can write du, partial derivative of dT u with respect to T at constant V, dT, dv plus partial derivative of u at constant V, dV.
好,对于一个恒定体积的过程,我们可以写出,等于偏u偏T,V不变,加上偏u偏V,T不变。
应用推荐