So, let's take a look at one of these rows in more detail to think about why this might be happening, and it turns out the reason that these glitches occur are because the sub shell structure predominates in certain instances, and that's where these glitches take place.

那么，让我们仔细地看一看其中一行,想一想为什么会这样，结果是这些小偏差的出现,是因为在一定情况下,亚壳层结构会产生重要影响，这正发生在小偏差出现的地方。

麻省理工公开课 - 化学原理课程节选

And the reason is simply because the energy that Z we gain in terms of moving up in z, 5 so from going to z equals 4 to z equals 5, -- is actually outweighed by the energy it takes to go into this new shell, to go into this new sub shell.

原因很简单,就是因为我们通过提升，所得到的能量--从，Z，等于，4，到，Z，等于，事实上比填充到这个新的壳层,新的亚壳层，所消耗的能量更多。

麻省理工公开课 - 化学原理课程节选

So when we talk about p orbitals, it's similar to talking about s orbitals, and the difference lies, and now we have a different value for l, so l equals 1 for a p orbital, and we know if we have l equal 1, we can have three different total orbitals that have sub-shell of l equalling 1.

当我们考虑ｐ轨道时，这和ｓ轨道的情形和相似，不同之处在于ｌ的值不一样，对于ｐ轨道，ｌ等于１,我们知道如果ｌ等于１,我们有３个,不同的轨道。

麻省理工公开课 - 化学原理课程节选

The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

我们今天要讨论的,另一个很重要的区别就是,在多电子原子中，轨道能力不仅仅依赖于，我们以前看到的外层，不仅仅依赖于n的值，而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

麻省理工公开课 - 化学原理课程节选