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But we've defined the enthalpy of those elements in their stable state at room temperature and pressure as zero, right?
但我们已经定义了这些,元素处于它们室温和常压下,最稳定的状态时的焓为零，对吧？
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What we define as zero is the enthalpy of every element in its natural state at room temperature and ambient pressure.
我们将零点定义为每种元素,在室温和正常大气压下,在其自然状态下的焓。
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It tells you what kind of molecule it is andgives you twovariables that are state variables You could have the volume and the temperature.
告诉你它是哪种分子,还给你了两个状态变量,它们可以是体积或温度。
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And the equation of state, pressure versus volume at constant temperature, is going to have some form, let's just draw it in there like that.
系统的态函数，恒温下压强比体积，变化曲线，就像这样。
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are all functions of state and parameters that we can control like temperature and pressure.
公式里面的全部都是态函数,我们控制态函数的参数比如温度或者压强。
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Hydrogen gas it's in its most stable state, right at room temperature and pressure.
和常压下氢气是氢元素，最稳定的状态，这个小“0“
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It's a state function, so we're at constant temperature and pressure, and now we want to consider some chemical change or a phase transition or you name it.
这就是态函数，我们处于恒定的温度和压强之下，然后考虑某些化学变化或者相变,或者你想考虑的东西。
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You know how pressure changes with temperature at constant volume if you know the equation of state.
如果你知道状态方程,知道在体积恒定的时压强如何随着温度变化。
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This is very different from the functions of state like pressure and temperature.
联系初末两态的整个过程,这与压强。
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Delta H of formation means the enthalpy of this compound minus the enthalpy of its constituent elements in their most stable state at room temperature and pressure.
生成焓就是这种组分,的焓减去它的所有组成元素,在室温和常压下处于,其最稳定的状态时的焓。
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Iron as an element is a solid. That's it's most stable state at room temperature and pressure, right, and so on. And then we can figure out heats of formation.
铁单质是固态,这是他在室温和常压下,最稳定的状态，然后我们,可以算出生成热，现在这个。
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We've done temperature, equations of state.
温度以及状态方程的概念。
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If I look at different points in my container during that path, I'm going to have to use a different value of pressure or different value of temperature That's not an equilibrium state, and that process turns out then to be an irreversible process.
如果我要研究在路径中容器里的,不同的点，我就得在容器里不同的点上使用,不同的压强值,或不同的温度值,实际上这不是个平衡态，这个过程是,不可逆过程。
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So now, this equation here relates three state functions together: the pressure the volume, and the temperature. Now, if you remember, we said that if you had a substance, if you knew the number of moles and two properties, you knew everything about the gas.
压强，体积和温度,大家应该还记得,我们提过，只要知道气体的摩尔数,和任意两个状态函数,就可以推导出其他的状态函数，这样，我们可以把它改写成。
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But because in many cases we can reasonably either model or measure equations of state, collect data for a material for its temperature, pressure, volume relations, then in fact if we can relate all these quantities to those then in fact we really can calculate essentially all of the thermodynamics. For the material.
但是因为在很多情况下,我们能够合理的给出状态方程的模型,或者通过收集一个物质的，温度，压强和体积之间的关系,来测量其状态方程，所以实际上我们可以给出压强等物理量,和热力学势之间的关系,并计算出所有的热力学势，对于给定的物质。
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