"It was like a giant jigsaw puzzle and the more we started to unearth and peel back the onion of who this guy was and what happened to him in the past and trying to truly understand the reason why he would be so obsessed with a specific case once we start to uncover these things about him we realized that once we explain one set of circumstances we needed to go even further with another set of circumstances."
VOA: standard.2010.02.27
So, what will start with on Monday is doing the most simple example of methane using these Lewis structure rules.
因此,下周一上课,我们会先以最简单的例子--甲烷开始,使用这些路易斯结构的规则。
We started talking about these on Wednesday, and what we're going to start with is considering specifically the wave functions for multi-electron atoms.
我们从周三开始讨论这些,而且我们将要以特别地考虑,多电子原子的波函数,为开始。
I don't expect you to start with one of these and then predict what is going to happen.
我没有期望你们能以其中的一个开始,然后推断发生了什么。
This is a little file I created, all right, and I'm going to start with a sequence of these things and walk them along, again I invite you to put comments on that handout so that you can follow what we're going to do. All right?
这是我创建的一个小文件,好,然后我回去以一系列这样的事情,开始然后进行下去,我还是想大家都在手册上做一些注释,这样我们就能对将要做的事情,做一个记录了,对不对?
Let's go into the third version of this and then start doing something with these constructs.
让我们进入这个程序的第三版,开始用这些概念来写点东西。
But first, I want to start with the assignment I gave you last time, and I asked you all to think about these two questions and write some things down.
首先,让我们看看,上节课留的作业,我要求你们都思考,下面这两个问题并写下感想
The water soluble vitamins tend to be used more immediately by the body not stored and excreted through the urine if consumed in excess, so the body can tolerate more variation in intake of these before you start getting toxicity than is the case with the vitamins on the right.
而水溶性维生素往往都立刻被身体所利用,不会被机体储藏,过剩部分由尿液排出,因此机体耐受过量水溶性维生素的能力,相比起右边这栏里的脂溶性维生素,可是要强得多了
So what we'll start with today is talking about the technique that's primarily used to actually experimentally figure out what these different energy levels are.
因此,我们今天首先要讨论的就是,最常用来在实验上,确定不同能级的技术。
Then we're going to actually use MO theory to describe bonding within these molecules, and we'll start with homonuclear diatomic molecules.
然后我们要利用MO理论,来描述这些分子内的成键,我们要讨论同核双原子分子。
So, if we start instead with talking about the energy levels, we can relate these to frequency, because we already said that frequency is related to, or it's equal to the initial energy level here minus the final energy level there over Planck's constant to get us to frequency.
如果我们从讨论能级开始,我们可以联系到频率上,因为我们说过频率和能量相关,或者说等于初始能量,减去末态能量除以普朗克常数。
And again, I want you to have practiced drawing these out in the form you always need to start with the sigma and then write the number of the orbital.
同样的,我希望你们,练习画这种图,你总是要从sigma开始,然后写出轨道数目。
So what we can say is look at each of these separately, so if we start with looking at the 2 p z orbital, the highest probability of finding an electron in the 2 p z orbital, is going to be along this z-axis.
我们可以来分别看看这些图,首先来看看2pz轨道,在2pz轨道里,找到电子的最大概率,是沿着z轴。
So essentially, we have two ethene or ethylene molecules here to start with where these blue are our 2 s p 2 hybrid orbitals, so you can see that for each carbon atom, one is already used up binding to another carbon atom.
本质上,我们从两个乙烯分子开始,蓝色的是2sp2杂化轨道,你可以看到,对于每一个碳原子,其中一个已经用来和另外一个碳原子成键。
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