If I now hybridize these, if I take these and I make four symmetric, now, these are just the sp3 orbitals.
如果我将他们杂化,然后形成4个对称的轨道,这就是sp3轨道。
sp3 PROFESSOR: OK, so it's 2 s p 3, and our second carbon is also 2 s p 3.
好的,是,第二个碳原子也是2sp3。
CH4 is sp3 carbon hybridization.
能容纳4个原子成键。
So what you see is actually a diminished lobe on the back part of this s p 3 orbital.
你们看到,在sp3轨道的后面部分,有个小叶。
This bond is polar, but again, as I alluded to earlier, because the carbon is centered in the tetrahedron, because of the sp3 hybridization, the molecule itself is symmetric and nonpolar.
这个键是非极性的,但是,我们断言过早,因为C是中心原子,由于sp3杂化,这个分子本身是非极性的且对称的。
All right, so in terms of s p 3 hybrid orbitals, let's combine all four together on one axis, because this is what's going to happen in an s p 3 carbon atom.
对于sp3杂化轨道,让我们把4个结合起来,因为这是sp3碳原子中发生的情况。
I have four bonds that are of equal energy, and he called this an sp3 hybrid.
我已经将4个能量相等的键画好了,他把这称为sp3杂化。
And specifically, when we give them a name it's very clear exactly which orbitals they come from combining, - we're calling these s p 3 orbitals -- that's because they come from combining 1 s orbital and 3 p orbitals.
特别的,我们命名它们,使得很容易看到它们是什么轨道结合而成的,我们叫这些轨道sp3轨道-,这是因为它们是由1s轨道,和3p轨道组合成的。
The reason that it's a sigma bond is sp3 because the s p 3 hybrid orbital is directly interacting with the 1 s orbital of the hydrogen atom, and that's going to happen on the internuclear axis, they're just coming together.
它是sigma键的原因,是因为,杂化轨道直接和氢原子1s轨道相互作用,它们作用发生在核间轴上,它们会到一起。
So s p 3 orbitals always have one huge lobe and one really little lobe.
所以sp3轨道总是有一个大叶,和一个非常小的叶。
So, this forms a tetrahedron, which forms the sp3 hybrid orbitals.
这就形成了一个四面体,它是由sp3杂化轨道形成的。
If it has 1 s and 3 p's, we call it s p 3.
如果它有1个s和3个p,我们叫它sp3。
All right, so that's s p 3 hybridization, but those aren't the only type of hybrid orbitals that we can form. Let's take a look at what happens if instead of combining all four orbitals, we just combine three of those orbitals, and what we'll end up with is s p 2 hybridization.
好了,这是sp3杂化,但这并不是我们可以,形成的唯一类型的杂化轨道,让我们来看看,不是四个轨道结合,我们仅仅结合3个轨道。
And, this is the shape. It's SP3 hybridized.
这是它的形状,sp3杂化。
Methane looks like this with the sp3 hybridization.
甲烷看起来就是sp3杂化的。
We have carbon, sp3 hybridization.
我们碳是sp3杂化。
So if we still have an angle of a 109 . 5 degrees, and again, we still have four unpaired electrons available for bonding, we can make one of those bonds with another s p 3 hybridized carbon, so we're going to make up one pair here.
如果键角仍然是109。,同样,我们还有4个未配对的电子可以用来成键,我们可以用其中的一个,和另外一个sp3杂化碳原子成键,这样我们可以组成一对。
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