• Gas phase single atom. So we don't have to deal with work function or any kind of energies associated with some condensed form of matter.

    气相的单原子,所以我们不需要再,处理功函数的问题,以及和凝聚态相关的能量问题。

    麻省理工公开课 - 固态化学导论课程节选

  • Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.

    路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。

    麻省理工公开课 - 化学原理课程节选

  • These are all one electron atoms, and they are gas, a single atom.

    这些都是单电子原子,它们都是气体,都是单原子。

    麻省理工公开课 - 固态化学导论课程节选

  • So let's go to a second clicker question here and try one more. So why don't you tell me how many possible orbitals you can have in a single atom that have the following two quantum numbers?

    让我们来看下一道题目,你们来告诉我,有多少个可能的轨道,含有这些量子数呢?

    麻省理工公开课 - 化学原理课程节选

  • Whereas in molecular orbital theory, what I'm telling you is instead we understand that the electrons are spread all over the molecule, they're not just associated with a single atom or a single bond.

    而在分子轨道理论里,我要告诉你们的时,我们任为电子分布在整个分子中,它们不仅仅是和,一个原子或者一个键有关。

    麻省理工公开课 - 化学原理课程节选

  • OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.

    后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。

    麻省理工公开课 - 固态化学导论课程节选

  • So we can actually pop an electron or eject an electron from any single orbital that is occupied within the atom.

    任何一个被占据轨道,打出一个电子,或者说发射出一个电子。

    麻省理工公开课 - 化学原理课程节选

  • So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.

    如果我告诉大家单个氢原子的能量,是负的,1312,千焦每摩尔。

    麻省理工公开课 - 化学原理课程节选

  • If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.

    而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。

    麻省理工公开课 - 化学原理课程节选

  • We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.

    我们以后会讲到,更加复杂的情况,那时候,不只有一个原子,但当我们讲,单个原子的时候,我们知道结合能,等于,负的Rydberg常数,除以n平方,所以它仅仅由n决定的。

    麻省理工公开课 - 化学原理课程节选

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