Gas phase single atom. So we don't have to deal with work function or any kind of energies associated with some condensed form of matter.
气相的单原子,所以我们不需要再,处理功函数的问题,以及和凝聚态相关的能量问题。
Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.
路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。
These are all one electron atoms, and they are gas, a single atom.
这些都是单电子原子,它们都是气体,都是单原子。
So let's go to a second clicker question here and try one more. So why don't you tell me how many possible orbitals you can have in a single atom that have the following two quantum numbers?
让我们来看下一道题目,你们来告诉我,有多少个可能的轨道,含有这些量子数呢?
Whereas in molecular orbital theory, what I'm telling you is instead we understand that the electrons are spread all over the molecule, they're not just associated with a single atom or a single bond.
而在分子轨道理论里,我要告诉你们的时,我们任为电子分布在整个分子中,它们不仅仅是和,一个原子或者一个键有关。
OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.
后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。
So we can actually pop an electron or eject an electron from any single orbital that is occupied within the atom.
任何一个被占据轨道,打出一个电子,或者说发射出一个电子。
So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.
如果我告诉大家单个氢原子的能量,是负的,1312,千焦每摩尔。
If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.
而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。
We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.
我们以后会讲到,更加复杂的情况,那时候,不只有一个原子,但当我们讲,单个原子的时候,我们知道结合能,等于,负的Rydberg常数,除以n平方,所以它仅仅由n决定的。
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