The leaders of ExxonMobil,Shell, ConocoPhillips and Chevron, as well as BP America, testified before a House of Representatives committee Tuesday.
VOA: standard.2010.06.15
So, from going from the shell of n equals 2, let's say, to the shell of n equals 3.
比如说,从n等于2到n,等于3壳层如何变化。
So, the chances of getting any activity from these inner shell of electrons are vanishingly small.
所以,内层电子间,进行反应的可能性,是很小很小的。
That's how I'm trying to play him and I think he's coming out of his shell a bit in Eclipse."
VOA: standard.2010.07.07
So when we talk about p orbitals, it's similar to talking about s orbitals, and the difference lies, and now we have a different value for l, so l equals 1 for a p orbital, and we know if we have l equal 1, we can have three different total orbitals that have sub-shell of l equalling 1.
当我们考虑p轨道时,这和s轨道的情形和相似,不同之处在于l的值不一样,对于p轨道,l等于1,我们知道如果l等于1,我们有3个,不同的轨道。
"The Gulf of Mexico response plans for ExxonMobil,Chevron, Conoco Phillips and Shell are virtually identical to BP's, and just as deficient."
VOA: standard.2010.06.15
We'll start up a shell and we'll try it. All right, we'll just get out of what we were doing here.
我们开一个shell然后试试,先退出现在的这个来。
Now, we get to draw some lessons out of this thing, so everybody who's feeling a little bit shell shocked from having been doing algebra and calculus and drawing pictures and feeling like they've been cheated into taking a class that looks far too much like economics, calm down we're going to actually talk right now.
下面我们从中总结点经验出来,那些因为代数和微积分计算还有绘图,而感到十分不爽的同学,你们是不是感觉被我忽悠了,才会选这门一点都不像经济学的课啊,稍安勿躁,我们马上切入正题
Because that will take care of all of the electrons that are capable of reacting, none of the inner shell electrons.
因为那样我们可以考虑到,除内层电子以外,所有可以发生反应的电子。
In other words, just want to know where the electron is somewhere within the shell radius of the ground state of atomic hydrogen anywhere.
换言之,我只是想知道,电子在哪,可以在氢原子基态下的半径,里面的任何地方。
But still, when we're talking about the radial probability distribution, what we actually want to think about is what's the probability of finding the electron in that shell?
但当我们讲到径向概率分布时,我们想做的是考虑,在某一个壳层里,找到电子的概率,就把它想成是蛋壳?
So if we actually go ahead and multiply it by the volume of our shell, then we end up just with probability, which is kind of a nicer term to be thinking about here.
乘以壳层的体积,我们就得到了概率,在这里从这个角度,理解问题更好一些,如果我们考虑的是。
We're saying the probability of from the nucleus in some very thin shell that we describe by d r.
某一非常薄的壳层dr内,一个原子的概率,你想一个壳层时。
The shell structure which people hadn't even thought of.
壳状结构,之前人们从未想到过。
So, what we can do to actually get a probability instead of a probability density that we're talking about is to take the wave function squared, which we know is probability density, and multiply it by the volume of that very, very thin spherical shell that we're talking about at distance r.
我们能得到一个概率,而不是概率密度的方法,就是取波函数的平方,也就是概率密度,然后把它乘以一个在r处的,非常非常小的,壳层体积。
So if you think of a shell, you can actually just think of an egg shell, that's probably the easiest way to think of it, where the yolk, if you really maybe make it a lot smaller might be the nucleus.
可以把它想成,个蛋壳,这也许是,最简单的思考办法,蛋黄如果,缩小非常多倍的话,就可以想象成核子。
So, basically what we're saying is if we take any shell that's at some distance away from the nucleus, we can think about what the probability is of finding an electron at that radius, and that's the definition we gave to the radial probability distribution.
本质上我们说的就是,如果我们在距离原子核,某处取一个壳层,我们可以考虑在这个半径处,发现电子的概率,这就是我们给出的,径向概率密度的定义。
That's kind of your shell that we're discussing.
我们讨论的大概就是,这种样子的壳层。
r And what that is the probability of finding an electron in some shell where we define the thickness as d r, some distance, r, from the nucleus.
在某个位置为,厚度为dr的壳层内,找到原子,的概率,我们来考虑下我们这里所说的。
Whatever the n number is, with the exception of helium, helium is the oddity because there's only two elements in n equals one shell.
无论n是多少,除了氦之外,氦是个特例,因为只有两个元素,在n为1的这一层。
shell What I have here is a Python shell, and I'm going to just show you some simple examples of how we start building expressions.
好,这是一个Python的,我会给大家看一些,关于写表达式的简单的例子。
So we actually only need two electrons to fill up the valence shell of hydrogen, remember that's because all we need to fill up is the 1 s.
我们其实只需要两个电子,就可以将氢的价壳层排满,要记得这是因为我们只需要排满,1,s,轨道。
So the 3 s 1, or any of the other electrons that are in the outer-most shell, those are what we call our valence electrons, and those are where all the excitement happens.
它们是经常发生激发情况的,那也是我们所看到,我们称之为价电子,它们是经常发生激发情况的。
If you took a 15 inch artillery shell moving at the velocity it typically goes at, and take that amount of kinetic energy versus the resistive capacity of a sheet of tissue paper, that's the scale that we're looking at here.
如果你有1个15英寸的炮弹,按照经典的速度移动,会消耗大量的动能,抵抗来自于一张薄纸的阻力,这就是我们在这儿看到的尺度。
And he gave a very good analogy in saying, "It was almost as incredible as if you'd fired a 15 inch shell at a piece of tissue paper, and it came back and hit you."
他还打过一个很好的比方:,“这就像是,你用个15英寸果壳,打到面巾纸上被弹回来打到你,一样不可思议,“
So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.
这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。
Think of it as that egg shell part.
我们可以。
This should make sense to you, because they don't, in fact, want to gain another electron, because that would mean that electron would have to go into a new value of n, a new shell, and that's really going to increase the energy of the system.
这对大家来说应该容易理解,因为它们实际上不想得到另一个电子,因为这意味着这个电子不得不,到一个新的,n,值更大的壳层上去,这将会增加系统的能量。
All in all, in the l shell, I have the possibility of eight different configurations.
所以总的来说,在L层,总共可能有八种不同构型。
And when you talk about n for an orbital, it's talking about the shell that shell is kind of what you picture when you think of a classical picture of an atom where you have 1 energy level, the next one is further out, the next one's further away.
当你们谈到,某个轨道的n时,你们说的是壳层,壳层就是,你想象,一个原子,的经典图像时的场景,你有一个能级,下一个再更远的地方,再下一个又更远。
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