So let's see, we started with 8 bonding electrons, and we used up only 4, so the answer is yes, we have 4 bonding electrons left.
那么让我们来看看,我们一开始有八个成键电子,然后只用掉了四个,因此答案应该是还有剩余,我们还剩下了四个成键电子。
So you can see that this is non-bonding, this is even worse than non-bonding, it's anti-bonding, because we're actually getting rid of electron density between the two nuclei.
所以你可以看到这是不成键的,它甚至比不成键还糟糕,它是反键,因为我们实际上是去掉了,两个原子核之间的电子。
so you can see that there is going to be two sets in antibonding, three sets in bonding for a net of one, giving us the single bond.
因此你能看到,反键轨道上有两组,三组成键,得到一组净成键,所以成的是单键。
So again, this is an anti-bonding orbital, and what you see is that there is now less electron density between the two nuclei than there was when you had non-bonding.
同样的,这是反键轨道,你们看到当你有反键轨道的时候,两个原子核中间的电子密度更小了。
All right, so we can now see a little bit of what the power of molecular orbital theory is in predicting what kind of bonds we're going to see in molecules, or whether or not we'll see this bonding occur at all.
好了,我们已经可以看到一点,分子轨道理论在预测分子中,所成的键或者分子,能不能成键方面的能力了。
You can see that there is no value in studying inner shell electrons to ask questions about bonding.
你应该了解考虑成键时,去考虑内层电子,是毫无意义的。
So what we'll have here is a trigonal planar case, and you can see that we only have three electrons that are set for bonding, so we'll add three hydrogens, and for b h 3, we'll get a stable structure here.
让电子劲量远离的时候,不用考虑它,这个例子是平面三角形,你可以看到,只有3个电子可以成键。
We see three bonding pairs so this is a triple bond, indeed a multiple bond.
我们看到3对成键电子所以这是一个三重键,它确实是多重键。
How many bonding electrons does c l have? All right. Let's see, we've got a mixed response here, it turns out it has two bonding electrons.
氯有多少成键电子?好,让我们来看看,大家的回答不太一致,结果应该是两个成键电子。
So you can see that polar covalency is a tendency towards ionic bonding.
所以你看得出极性共价就是,趋向离子键的。
So we'll start to look at molecules and we'll see if we take two atoms and we fill in our molecular orbital and it turns out that they have more anti-bonding orbitals than bonding, that's -- a diatomic molecule we'll never see.
我们要看开始看一看分子,并且我们会发现如果我们,取两个原子并且填入分子轨道,结果是它们的反键轨道,比成键轨道更多,这就是-一个我们不会看到的二元子分子。
So any time you see a star that means an anti-bonding orbital.
任何时候你看到有个星,这意味着它是反键轨道。
That's what we see are involved in bonding.
那也是我们所看到的结合的电子。
if we move up one of our electrons into an empty p orbital, what were going to see is now we have three unpaired electrons that are ready for bonding.
教授:嗯,如果我们把其中,一个电子填入p轨道。
So it helps us predict, will we see this, for example, h 2, which we're going to be about to do, we'll see is stabilized because it has more bonding than anti-bonding.
这帮助我们预测,我们等会会看到,比如H2O,我们等会要讲到,我们会看到它更稳定是,因为成键比反键更多。
PROFESSOR: Two. OK, good. So again, we're going to see that we have a bonding order of 0.
两个,OK,很好,同样的,我们会看到键序是0。
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