-
But luckily for us, there's a classical equation of motion that will, in fact, describe how the electron and nucleus change position or change their radius as a function of time.
但幸运的是，有一个,经典方程描述了电子和核子,位置或者它们直接的距离是,如何随时间变化的。
-
So, the size still for an s orbital is larger than for a d orbital, but what we say is that an s electron can actually penetrate closer to the nucleus.
轨道的尺寸比,ｐ轨道还是要大，但我们说的是ｓ轨道可以,穿透到更接近原子核的地方。
-
OK, so all I do is I take into account that I've got all the positive charge, whatever it is, it's a nucleus.
我做的全部是考虑,我得到所有的正电荷，无论是什么，都是一个核。
-
And that's essentially what we saw people have more nucleus accumbens activation priority choice " they are more likely to choose that stock.
这就是我们得到的结果,在作出选择时，受试者的伏隔核活动越多,他们就越有可能选择“股票。
-
Why don't bacteria need a distinct nucleus and that's necessary in a human cell?
为什么细菌不需要单独的细胞核,而对人类细胞则为必需
-
But what's important is not where that most probable radius is when we're talking about the z effective it feels, what's more important is how close the electron actually can get the nucleus.
但重要的不是,最可能半径,当我们谈论它感到的有效电荷量的时候，更重要的是,电子实际上。
-
We are expecting to see that it decreases because it's feeling a stronger pull, all the electrons are being pulled in closer to the nucleus, so that atomic size is going to get smaller.
我们将看到它是减小的,因为电子会感受到越来越强的吸引力，所有的电子将会被原子核拉得越来越近，所以原子半径将越来越小。
-
We looked at the wave functions, we know the other part of solving the Schrodinger equation is to solve for the binding energy of electrons to the nucleus, so let's take a look at those.
我们看过波函数，我们知道解,薛定谔方程的其他部分,就是解对于原子核的电子结合能，所以我们来看一看。
-
And the reason that they're the least sheilded is because they can get closest to the nucleus, so we can think of them as not getting blocked by a bunch of other electron, because there's some probability that they can actually work their way all the way in to the nucleus.
它们最不容易被屏蔽的原因,是因为他们可以更加接近原子，所以我们可以认为它们,最不容易被其它原子阻挡住，因为它们有一定的概率,离原子核非常近。
-
There's some probability that it can get very, very close the nucleus, and that probability is actually substantial.
有一定的概率,它能非常非常接近原子核，这个概率是相当大的。
-
And we know as we go across a row in the periodic table, what's happening is that z effective or the effective pull on the nucleus is increasing.
而我们知道沿着周期表的某一行向右看，有效核电量,或者说原子核的有效引力是在逐渐增大的。
-
So, remember when we talk about Coulomb force, what's holding the nucleus and the electron together, there's 2 things we need to think about.
还记得我们在讨论库仑力的时候，提到是什么将原子核与电子束缚在一起时，有两点需要考虑。
-
And so, the radial probability density at the nucleus is going to be zero, even though we know the probability density at the nucleus is very high, that's actually where is the highest.
所以径向概率密度,在核子处等于零，虽然我们知道在，核子处概率密度很大,实际上在这里是最大的，这是因为。
-
It's not complete and it's not accurate, but it's OK to kind of think of it in terms of how far we're getting away from the nucleus.
这并不完整，也不精确，但是假如只是想想,我们在离原子核越来越远的话，还是没问题的。
-
So, all that's left is the helium nucleus, two protons, two neutrons.
仅留下氦核，两个质子，两个中子。
-
The first is this the z effective, or how much charge is actually in the nucleus that's felt, Z or the I guess we would say the z, how much the charge is on the nucleus that holds it close together.
第一个是有效核电量，或者说实际感受到的核电荷量，又或者我想我可以说就是，使它们保持在一起的,原子核的电荷量。
-
So let's take two cases of shielding if we're talking about, for example, the helium, a helium nucleus or a helium atom.
所以我们来对屏蔽举两个例子,如果我们在讨论氦，举例来说一个氦原子核或者氦原子。
-
And what is discussed is that for a 1 s hydrogen atom, that falls at an a nought distance away from the nucleus.
我们讨论了对于氢原子１ｓ轨道，它的最可能半径在距离原子核ａ０处。
-
What we're going to do in forming a molecule is just bring these two orbitals close together such that now we have their nucleus, the two nuclei, at a distance apart that's equal to the bond length.
我们在形成一个分子时要做的就是,把这两个轨道放到一起,这样我们有他们的原子核，两个原子核，它们之间的距离为键长。
-
So what is actually going to matter is how closely that electron can penetrate to the nucleus, and what I mean by penetrate to the nucleus is is there probability density a decent amount that's very close to the nucleus.
所以实际上有关系的是,电子可以穿越至原子核有多近,我所指的穿越至原子核是,这里有一定数量的概率密度,可以距离原子核非常近。
-
So again, what we're saying here is that it is most likely in the 3 s orbital that we would find the electron 11 and 1/2 times further away from the nucleus than we would in a around state hydrogen atom.
同样我们,这里说的是,氢原子３ｓ轨道中,最可能找到电子的地方,是基态的１１．５倍。
-
For example, when we're talking about radial probability distributions, the most probable radius is closer into the nucleus than it is for the s orbital.
举例来说当我们讨论径向概率分布时,距离原子核最可能的半径是，比s轨道半径,更近的可以离原子核有多近。
-
So, shielding happens when you have more than one electron in an atom, and the reason that it's happening is because you're actually canceling out some of that positive charge from the nucleus or that attractive force with a repulsive force between two electrons.
所以当你们在原子中有多于一个电子,屏蔽就会发生，它之所以会发生的原因是,你们实际上抵消了,一些来自原子核的正电荷,或者来自吸引力,在两个电子之间。
-
The reason it's aluminum is because aluminum has a lower z effective, so it's not being pulled in as tightly by the nucleus, and if it's not being pulled in as tightly, you're going to have to put in less energy in order to ionize it, so that's why it's actually going to have the smaller ionization energy.
原因是,铝的有效核电量更少，所以没有被原子核束缚得更紧，而如果没有被束缚得更紧，你为了电离它所需要注入的能量也就更少，这就是,它的电离能会更低的原因。
-
In this case the shape is - there's a cell body in the center here so this is where the nucleus is and where all the transcription, production of proteins take place here.
在这个细胞中,中间部位是细胞体,细胞核位于其中央,转录以及翻译过程均发生于此
-
A kind of consequence of this is if we're thinking about a multi-electron atom, which we'll get to in a minute where electrons can shield each other from the pull of the nucleus, we're going to say that the electrons in the s orbitals are actually the least shielded.
这样的一个后果就是,如果我们考虑一个多电子原子，我们等会就会讨论到它,电子会互相,屏蔽原子核的吸引，我们说ｓ轨道电子,更不容易被屏蔽。
-
That was Cartesian space. When I plot r as a distance out from the nucleus that is sort of our simple-minded planetary model. Now let's look at energy.
笛卡尔坐标系，当我用r表示,离原子核的距离时，那只是我们头脑中简单的,类似行星的模型，现在我们看一下能量问题。
-
So, if I kind of circle where the probability gets somewhat substantial here, you can see we're much closer to the nucleus at the s orbital than we are for the p, then when we are for the d.
我把概率,很大的地方圈出来，你们可以看到在ｓ轨道上,比ｐ轨道更接近原子核，最远是ｄ轨道。
-
So what this means is that unlike s orbitals, they don't have the exact same shape at any radius from the nucleus.
这意味着和ｓ轨道不同，它们在离原子核不同距离处的形状不是完全一样的。
应用推荐