• So instead of being equal to negative z squared, now we're equal to negative z effective squared times r h all over n squared.

    这里不再等于-z的平方,现在我们等于-有效的z的平方,乘以RH除以n的平方。

    麻省理工公开课 - 化学原理课程节选

  • And that's going to be equal to negative z effective squared times r h over n squared.

    有效的z的平方,乘以RH除以n的平方。

    麻省理工公开课 - 化学原理课程节选

  • So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.

    我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来,我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。

    麻省理工公开课 - 化学原理课程节选

  • We also know how to figure out the energy of this orbital, and we know how to figure out the energy using this formula here, which was the binding energy, -Rh which is negative r h, we can plug it in because n equals 1, so over 1 squared, and the actual energy is here.

    我们知道如何算出,这个轨道的能级,而且我们知道如何,用这个公式,算出能量,也即是结合能,等于,我们把n等于1代进来,所以除以1的平方,这就是能量。

    麻省理工公开课 - 化学原理课程节选

  • So, if we just rearrange this equation, what we find is that z effective is equal to n squared times the ionization energy, IE all over the Rydberg constant and the square root of this.

    我们可以发现有效的z等于n的平凡,乘以电离能除以里德堡常数,这些所有再开方,所以等于n乘以,除以RH整体的平方根。

    麻省理工公开课 - 化学原理课程节选

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