• We can graph out what this is where we're graphing the radial probability density as a function of the radius.

    我们可以,画出它来,这是径向概率密度,作为半径的一个函数图。

    麻省理工公开课 - 化学原理课程节选

  • So I mentioned you should be able to identify both how many nodes you have and what a graph might look like of different radial probability distributions.

    我说过你们要能够辨认,不同的径向概率分布有多少个节点,以及它的图画出来,大概是什么样的。

    麻省理工公开课 - 化学原理课程节选

  • It's good to have a vector pointing in the radial direction of length one.

    所以引入这么一个模长为 1,方向沿圆心向外辐射的矢量作用很大

    耶鲁公开课 - 基础物理课程节选

  • So, you should know that there's four radial nodes, right, we have 5 minus 1 minus l -- is there a question?

    你们要记住这里有四个节点,对吧,5减去1减去l,有问题吗?

    麻省理工公开课 - 化学原理课程节选

  • So if we superimpose our radial probability distribution onto the Bohr radius, we see it's much more complicated than just having a discreet radius.

    为波尔半径,这其实比分立的轨道,要复杂很多,我们可以有任何的半径,但有些半径的概率。

    麻省理工公开课 - 化学原理课程节选

  • But you should see that there are four radial nodes here since we have a 5 s orbital.

    但你们应该知道,这里有4个节点,因为它是5s轨道。

    麻省理工公开课 - 化学原理课程节选

  • So here, what I'd like you to do is identify the correct radial probability distribution plot for a 5 s orbital, and also make sure that it matches up with the right number of radial nodes that you would expect.

    这里,你们要辨认,哪个是5s轨道的正确概率分布,并且确保它和你们,预期的节点数相符合。

    麻省理工公开课 - 化学原理课程节选

  • So, I'm asking very specifically about radial nodes here, how many radial nodes does a hydrogen atom 3 d orbital have?

    我问的是径向节点,这里3d轨道的径向节点有多少个?

    麻省理工公开课 - 化学原理课程节选

  • OK. So let's actually go to a clicker question now on radial probability distributions.

    好,让我们来做一个关于,径向概率分布的题目。

    麻省理工公开课 - 化学原理课程节选

  • So that's why we have this zero point here, and just to point out again and again and again, it's not a radial node, it's just a point where we're starting our graph, because we're multiplying it by r equals zero.

    这就是为什么在这里有个零点,我需要再三强调,这不是径向零点,他只是我们画图的起始处,因为我们用r等于0乘以它。

    麻省理工公开课 - 化学原理课程节选

  • OK. So we should be able to figure this out for any orbital that we're discussing, and when we can figure out especially radial nodes, we have a good head start on going ahead and thinking about drawing radial probability distributions.

    我们可以将这种方法,用于任何轨道,当我们可以算出有多少个径向节点的时候,我们就为画出径向概率分布,开了个好头。

    麻省理工公开课 - 化学原理课程节选

  • Yup, zero radial nodes. So, for a 2 p orbital, all the nodes actually turn out to be angular nodes.

    没有,对于2p轨道,所有的节点都是角向节点。

    麻省理工公开课 - 化学原理课程节选

  • So, I think we're a little bit out of time today, but we'll start next class with thinking about drawing radial probability distributions of more than just the 1 s orbital.

    快没时间了,但我们,在下节课会讲,1s轨道以外的,径向概率分布。

    麻省理工公开课 - 化学原理课程节选

  • At each point, er is a different vector pointing in the radial direction of length one.

    矢量 er 在每一点处都不同,方向都从圆心指向该点,模长为1

    耶鲁公开课 - 基础物理课程节选

  • So what we're graphing here is the radius as a function of radial probability.

    我们要画的是径向概率,作为半径的函数分布。

    麻省理工公开课 - 化学原理课程节选

  • So, the example that we took on Monday and that we ended with when we ended class, was looking at the 1 s orbital for hydrogen atom, and what we could do is we could graph the radial probability as a function of radius here.

    周一我们,最后讲到了,粒子是氢原子1s轨道,我们可以画出,这幅径向概率分布曲线。

    麻省理工公开课 - 化学原理课程节选

  • so when we think about what it is that this radial probability distribution is telling us, it's telling us that it is most likely that an electron in a 2 s orbital of hydrogen is six times further away from the nucleus than it is in a 1 s orbital.

    我们来讨论一下这个径向概率分布,告诉了我们什么,它告诉我们,对于氢原子2s轨道的电子,最可能位置是1s轨道的6倍。

    麻省理工公开课 - 化学原理课程节选

  • So, this should be pretty straight forward, 100% let's see if we can get close to a 100% on this one, which is how many radial nodes does a 4 p orbital have?

    很简单,让我们来看看这题,我们是不是可以接近%,对于一个4p轨道,它有多少个节点?,给你们10秒钟?

    麻省理工公开课 - 化学原理课程节选

  • We'll introduce in the next course angular nodes, but today we're just going to be talking about radial nodes, psi and a radial node is a value for r at which psi, and therefore, 0 also the probability psi squared is going to be equal to zero.

    将会介绍角节点,但我们今天讲的是,径向节点,径向节点就是指,对于某个r的值,当然,也包括psi的平方,等于,当我们说到s轨道时。

    麻省理工公开课 - 化学原理课程节选

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