We didn't just need that n, not just the principle quantum number that we needed to discuss the energy, but we also need to talk about l and m, as we did in our clicker question up here.
我们不仅需要n,不仅要这个可以,决定能量的主量子数,还需要m和l,就像我们做这道题这样。
b The repulsive term goes as some constant lower case b divided by R to the n. N is not the quantum number.
这种斥力很想一个固定的小写字母,被R到n分开的话,N不是量子数。
So, there are 2 different things that we can compare when we're comparing graphs of radial probability distribution, and the first thing we can do is think about well, how does the radius change, or the most probable radius change when we're increasing n, when we're increasing the principle quantum number here?
当比较这些径向概率分布图,的时候,我们可以比较两个东西,第一个就是考虑当我们增加n,当我们增加主量子数的时候,半径怎么变,最可能半径怎么变化?
So, it turns out that n is not the only quantum number needed to describe a wave function, however. There's two more you can see come out of it.
事实上,n不是描述一个波函数需要的,唯一的量子数,你们可以看到,还需要,两个量子数。
Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.
芯电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子。
Specify the quantum number n and divide by Z.
只需说明n的具体值,并用Z去除就行了。
l So, if we're talking about a 4 p orbital, and our equation is n minus 1 minus l, the principle quantum number is 1 4, 1 is 1 -- what is l for a p orbital?
我们方程是n减去1减去,主量子数是,4,1是1,--p轨道的l是多少?,学生:
And we can generalize to figure out, based on any principle quantum number n, how many orbitals we have of the same energy, n and what we can say is that for any shell n, there are n squared degenerate orbitals.
我们可以总结出来,在,主量子数为n的情况下,同一个能量上,有多少个轨道,我们可以说,对任何壳层,有n平方个简并轨道。
n So the velocity is given by this product of the quantum number n Planck constant 2 pi mass of the electron time the radius of the orbit, which itself is a function of n.
速度是量子数,普朗克常数2π乘以轨道半径的值,它自身也是n的函数。
n l So negative e, which is sub n l, because it's a function of n and l in terms of quantum numbers.
也就是负的,E,下标是,因为它是一个,关于量子数,n,和,l,的函数。
psi So we're going to for psi, and before that, we're going to figure out that instead of n just that one quantum number n, we're going to have a few other quantum numbers that fall out of solving the Schrodinger equation for what psi is.
我们要讲到,但在这之前,我们已经知道了,主量子数,现在我们需要知道,其他一些,解psi的薛定谔方程,所需要的量子数。
And when we make these comparisons, one thing I want to point out is that we need to keep the constant principle quantum number constant, so we're talking about a certain state, so we could talk about the n equals 2 state, or the n equals 3 state.
当我们做这些比较时,我想指出的一件事是,我们需要保持常量原则,保持量子数是常数,所以我们在讨论一个确定的态时,我们可以谈论n等于2的态,或者n等于3的态。
The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.
我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。
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