And the point that I also want to make is the way that they differ, z effective actually differs from the total charge in the nucleus due to an idea called shielding.

我也想指出的一点是它们不同的方式,有效的z事实上不同于原子核的，总电荷量,因为屏蔽效应。

麻省理工公开课 - 化学原理课程节选

z And what you need to remember is if the z 8 is equal to eight or greater, such as oxygen being the cut-off point, this sigma 2 p orbital is actually lower in energy than the pi 2 p orbitals, the molecular orbitals.

你们要记住如果,等于或者大于，就像O是分界点，这时sigma2p轨道,比π2p轨道能量更低。

麻省理工公开课 - 化学原理课程节选

So it's OK to not specify. I want to point out, pz whether you're in the p x, the p y, or the p z, unless a question specifically m asks you to specify the m sub l, which occasionally will happen, but if it doesn't happen you just write it like this.

我想指出的是，无论你在px，py或，除非一个问题特别地,让你指出l下面的，这种情况有时会发生，这样就可以了,但是如果它不做要求你们写成。

麻省理工公开课 - 化学原理课程节选