It turns out, and we're going to get the idea of shielding, so it's not going to actually +18 feel that full plus 18, but it'll feel a whole lot more than it will just feel in terms of a hydrogen atom where we only have a nuclear charge of one.
结果是我们会有,屏蔽的想法,所以它不会是完整的,但是它会比原子核电荷量,吸引力要大很多,只有1的氢原子的。
Cv+R=Cp Cv is equal, oh Cv plus R is equal to Cp it's a relationship that we had up here that we wanted to prove.
我们就得到了,我们一开始,想要证明的。
So if we have total +2 and complete shielding -1 where that can actually negate a full positive charge, because remember our nucleus is plus 2, +1 one of the electrons is minus 1, so if it totally blocks it, all we would have left from the nucleus is an effective charge of plus 1.
抵消一个完全的正电荷,因为记住我们的原子核是,其中一个电子是,所以如果它完全挡住了它,我们从原子核中留下的,全部有效电荷就是,所以,在我们的第一个例子中,我们的第一种极端情况。
If I reduce that it would be 3 plus t of b minus 3, so in general 3*k+t this is 3 k plus t of b minus k. OK.
把b减去一个,在外面加个3就可以了,因此也就是。
What about H2 plus? What would that look like?
那么H2+呢,这看起来像什么呢?
dU=dq+dw Still know that du is dq plus dw.
所以。
r+ And let's say that sodium has a radius, r plus, r- and chlorine has a radius, r minus, when r is very large in comparison to the radii of the ions, I don't need to draw them this way.
让我们假设钠有半径,是,氯也有半径,是,当r比离子半径大很多的时候,我不需要这样来描述。
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