px So we're talking about pi carbon 2 p x, 2px because it's the x axes combining to carbon 2 p x.

我们讨论的是π碳，因为它在x轴结合成碳。

麻省理工公开课 - 化学原理课程节选

So let's fill it out in this way, 2p keeping in mind that we're going to fill sigma out the pi 2 p's before the sigma.

让我们这样填上去，记住我们先填π,轨道再填。

麻省理工公开课 - 化学原理课程节选

Remember, we didn't hybridize the 2 p y orbital, so that's what we have left over to form these pi bonds.

记住，我们并没有杂化2py轨道，这是我们剩下的那个行成了π键。

麻省理工公开课 - 化学原理课程节选

There's not two bonds, that's one pi bond, and the reason is because it's 2 p orbitals coming together, and remember p orbitals have electron density above and below the axis, so when they come together, it kind of looks like one bonds, but essentially what we have here is one pi bond.

这不是两个键，这是一个π键，因为这是两个2p轨道组合而成的，记住p轨道在键轴之上,和键轴之下都有电子密度，当它们靠近时，这看着很像两个键，但本质上它是一个π键。

麻省理工公开课 - 化学原理课程节选

And again, this is between the p orbitals, these are not hybrid orbitals, so when we name this bond we're going to name it as a pi bond here, because it's between two p orbitals, and it's going to be between the carbon 2 p y orbital, and the other carbon 2 p y orbital.

同样，这是在p轨道之间的，它们不是杂化轨道，所以当我们命名这个键时,我们要命名它为π键，因为它在两个p轨道之间，而且是在碳2py轨道，和另一个碳2py轨道之间。

麻省理工公开课 - 化学原理课程节选

So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.

这就是苯环里的两种键，我们还剩一种，那就是这些p轨道之间，形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。

麻省理工公开课 - 化学原理课程节选

All right, so what we see here is we have our sigma bond that's along the internuclear axis here, but we also have a pi bond, because each of these atoms now has electrons in it's in a p orbital, so we're going to overlap of electron density above and below the bond.

这里我们看到sigma键,是沿着核间轴的，但我们还有一个π键，因为每个原子的p轨道上,都有电子，所以电子密度在键的上面,和下面都有电子密度交叠。

麻省理工公开课 - 化学原理课程节选