-
So even though we see a nodal plane down the center, I just want to really point out that it's only when we have a nodal plane in the internuclear or the bond axis that we're calling that a pi orbital.
虽然在中间有个节面，我想要指出的是,只有节面在核间轴,或者键轴上时,我们才叫它π轨道。
-
The reason that I wanted to point out this nodal plane here is because this is why it is called a pi orbital.
我指出这个节面的原因是因为,它就是为什么这个叫做π轨道的原因。
-
sigma That is one pi orbital. There is one sigma, one pi and there is a second pi, and that is how we are getting the triple bond.
那是一个pi轨道，有一个，一个pi，还有第二个pi轨道，这就是我们如何得到三线态的。
-
These are the ones that are coming right out at you, so this is going to be on a second pi orbital.
它们朝向你们，所以这里有另一个π键。
-
Pi orbitals are a molecular orbital that have a nodal plane through the bond axis.
轨道是沿着键轴,有节面的分子轨道。
-
Another thing I want to point out about every sigma orbital that you see, and it will make more sense when we contrast it with pi orbitals later.
另外一个我要指出的事情就是,关于每个sigma轨道你能看到,当我们把它和π轨道对比的时候会看的更清楚。
-
Do you predict that this will be a sigma or a pi orbital?
你们认为这是sigma轨道还是π轨道？
-
So z equals 7 -- this is the cut-off where, in fact, the sigma orbital is going to be higher in energy than the pi 2 p orbitals.
所以z等于7-这是分界点，实际上，sigma轨道能量,要比π2p轨道高。
-
And this will be called pi of 2py molecular orbital.
我们会称它为2py分子轨道上的π键。
-
Remember, we didn't hybridize the 2 p y orbital, so that's what we have left over to form these pi bonds.
记住，我们并没有杂化2py轨道，这是我们剩下的那个行成了π键。
-
You can see that we have two unpaired electrons in this molecule here one in the pi 2 p x star, and one in the pi 2 p y star orbital.
你们可以看到我们这个,分子力有两个未配对电子,一个在π2px星，一个在π2py星轨道。
-
So it already should make sense why we have that p orbital there, in order to form a pi bond, we're going to need a p orbital.
这里有p轨道是很合理的,为什么我们在这里有P轨道，为了形成一个π键，我们需要一个p轨道。
-
z And what you need to remember is if the z 8 is equal to eight or greater, such as oxygen being the cut-off point, this sigma 2 p orbital is actually lower in energy than the pi 2 p orbitals, the molecular orbitals.
你们要记住如果,等于或者大于，就像O是分界点，这时sigma2p轨道,比π2p轨道能量更低。
-
So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.
这就是苯环里的两种键，我们还剩一种，那就是这些p轨道之间，形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。
-
All right, so what we see here is we have our sigma bond that's along the internuclear axis here, but we also have a pi bond, because each of these atoms now has electrons in it's in a p orbital, so we're going to overlap of electron density above and below the bond.
这里我们看到sigma键,是沿着核间轴的，但我们还有一个π键，因为每个原子的p轨道上,都有电子，所以电子密度在键的上面,和下面都有电子密度交叠。
应用推荐