1.77245... I don't want to knowwhat the square root of pi is.

VOA: standard.other

There's absolutely no reason I couldn't have switched it around and said that instead the pi orbitals form between these atoms instead of those first atoms I showed.

我完全没有理由,不能把它转过来,现在π键在这些原子间,而不是我开始展示的那些原子间。

麻省理工公开课 - 化学原理课程节选

So I got into Pi Beta Phi which is fairly new here.

所以我进了Pi Beta Phi,一个挺新的联谊会。

加入女生社团 - SpeakingMax英语口语达人

The reason that I wanted to point out this nodal plane here is because this is why it is called a pi orbital.

我指出这个节面的原因是因为,它就是为什么这个叫做π轨道的原因。

麻省理工公开课 - 化学原理课程节选

e The charge on the anion times minus e, so there is the minus e squared, 0R0 and divided by 4 pi epsilon zero r naught, because now I am evaluating this function at r naught, one minus one over n where n is the Born exponent.

阴离子的电荷乘以，因此会有-e的频繁，除以4πε,因为现在我用r圈评估这个函数，1-1/n，n是波恩指数。

麻省理工公开课 - 固态化学导论课程节选

So if I try to rotate my 2 atoms, you see that I have to break that pi bond, because they need to be lined up so that the electron density can overlap.

如果我要试着转动两个原子，你会看到我必须要打破一个π键，因为他们需要连接起来,让那些电子能够重叠。

麻省理工公开课 - 化学原理课程节选

So would you expect this to be a pi bond or a sigma bond her PROFESSOR: OK, so I'm hearing some mixed answers.

你们觉得这是一个π键还是sigma键？,我听到有不同的答案。

麻省理工公开课 - 化学原理课程节选

In contrast, if we talk about a double bond, what we're now talking about is having both a sigma bond and also one pi bond. And I apologize, I intended to set this up right before class, but that didn't happen today.

相反，如果我们讨论一个双键，我们现在讨论的是,一个sigma键和π键，抱歉，我应该在课前就把这个装好的，今天没装好。

麻省理工公开课 - 化学原理课程节选

So this is very similar to what we saw i n terms of sigma orbitals and pi orbitals.

这和我们在sigma轨道,和π轨道中看到的很像。

麻省理工公开课 - 化学原理课程节选