And what I want to point out here is this angular dependence for the p orbitals for the l equals 1 orbital.
这里我要指出的是,l等于1的p轨道随角度的变化。
So for example I defined p, remember back over here, as a Cartesian point, but I can actually ask for its polar form.
我可以要求返回它的极坐标形式,这里对我是可访问的,好,这很棒,请再记另外一个为什么。
And our job is to find out what is the mathematical description of this path, this line in p-V's case that connects these two point.
我们的任务,就是找出,描述这条曲线的方程。
Let's just suppose, as seems likely, that none of the P-functioning is occurring, at some point during sleep.
我们就这样设想一下,在睡眠的某个时间点上,没有任何人格功能性。
z And what you need to remember is if the z 8 is equal to eight or greater, such as oxygen being the cut-off point, this sigma 2 p orbital is actually lower in energy than the pi 2 p orbitals, the molecular orbitals.
你们要记住如果,等于或者大于,就像O是分界点,这时sigma2p轨道,比π2p轨道能量更低。
Let's let p be Cartesian point, and we'll give it a couple of values. OK?
然后我们给它赋值,好不好?,发生了什么?
In that case point p 1 doesn't correspond to this point, it actually corresponds to the point of radius 2 and angle 1, which is about here.
基本上也就是说这是第一个点1,这是第二个点,把它们的值加到一起,然后我就得到了目标点,好,这听起来挺不错的。
OK, now, if I actually do this, and I'm going to show you the example, I just, what did I type over there, I got p was a c point.
传入了其他的参数,好,现在,如果我,实际上要做这个的话,我要给大家看个例子。
And I can give a name to that, so c p 1 and c p 2 are both going to point to that.
为这个实例分配了空间,现在它是空的,实际上也不完全是空的。
p1 But if I say, are p 1 and p 2 the same point, it says yes.
和p2是不是同一个点,It,says,no。,返回的结果是肯定的,在这里我有个要强调的点,这个例子里发生的是。
p2 It's taking the name p 1 and it's changing its value to point to exactly what p 2 points to.
我要把p1赋值为1,这个操作有什么用呢?,这个操作把p1这个名字的,指针的值改变让它。
We'll make p a new point, ok?
让我们再试一次?
So when I type, I'm sorry, I shouldn't say type, c point although I would have typed it, p dot x, here's what basically happens.
处于特定点的实例的这个概念,我知道它来自于这个类,这个类,when,I,write,因此当我输入,抱歉,我不该说输入的,当我写,虽然我需要输入它,p,x的时候。
So it's OK to not specify. I want to point out, pz whether you're in the p x, the p y, or the p z, unless a question specifically m asks you to specify the m sub l, which occasionally will happen, but if it doesn't happen you just write it like this.
我想指出的是,无论你在px,py或,除非一个问题特别地,让你指出l下面的,这种情况有时会发生,这样就可以了,但是如果它不做要求你们写成。
But there's something you'll note here also when I point out the case of the 2 s versus the 2 p, which is what I mentioned that I would be saying again and again, which is when we look at the hydrogen atom, the energy of all of the n equals 2 orbitals are exactly the same.
但是这里有一些事情你们也会注意到,当我指出2s和2p的情况,我之前提过,我会一次又一次的说,我们在观察氢原子的时候,2层轨道的所有n的能量,是完全相同的。
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