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VOA: standard.2010.06.05
People make really stupid decisions and so as you know in this course with P sets there are three axes that we look at when evaluating your code.
人们做了一个愚蠢的决定,在这个课程上,通过习题集,当执行你的代码的时候,有三个评估方面。
We'll make p a new point, ok?
让我们再试一次?
Again, we're going to take the linear combination of those p atomic orbitals and make what are called pi or some more sigma molecular orbitals.
同样的,我们需要得到,原子p轨道的线性组合,然后组成我们所说的,π分子轨道或者sigma分子轨道。
So we'll assume just to make life simple, that the total quantity produced is 1 -P.
为了简化,我们假设,总产量是1-P
And then we're going to name the atomic orbitals that make it up, and it's being made up of a carbon 2 s p 3 orbital, and a hydrogen 1 s orbital.
然后我们要命名,组成它的原子轨道,它是由碳2sp3轨道,和氢原子1s轨道组成。
That should make sense because they come from combining s orbitals and p orbitals.
这会产生一定的效果,因为他们由s轨道和p轨道合成。
So it already should make sense why we have that p orbital there, in order to form a pi bond, we're going to need a p orbital.
这里有p轨道是很合理的,为什么我们在这里有P轨道,为了形成一个π键,我们需要一个p轨道。
So these names, they don't really make any sense why they're called past s p and f, and it turns out that it comes from spectroscopy terms that are pre-quantum mechanics where, for example, this is called the sharp line, I think the principle, the diffuse, and the fundamental.
看到这些名字,你会发现,它们为什么叫s,p,f是没什么道理的,事实上,它们来源于,量子力学之前的光谱学中的术语,例如,它们分别叫做锐线,我认为是主线,漫射和基本。
So if we still have an angle of a 109 . 5 degrees, and again, we still have four unpaired electrons available for bonding, we can make one of those bonds with another s p 3 hybridized carbon, so we're going to make up one pair here.
如果键角仍然是109。,同样,我们还有4个未配对的电子可以用来成键,我们可以用其中的一个,和另外一个sp3杂化碳原子成键,这样我们可以组成一对。
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