sigma2sp It's going to be a sigma bond. So, we have sigma 2 s p, carbon 2 s p. So they're two s p bonds combining.

是sigma键，我们有，碳2sp。，所以它们是两个sp键结合。

麻省理工公开课 - 化学原理课程节选

So it's going to be a sigma bond, 1s and we have oxygen 2 s p 3 and hydrogen 1 s.

它是sigma键，我们有氧2sp3和氢。

麻省理工公开课 - 化学原理课程节选

And the last bond that we have here is a carbon-carbon bond, and this is our last p orbitals that are coming together.

最后一个键是碳碳键，这是最后一个组合的p轨道。

麻省理工公开课 - 化学原理课程节选

So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.

所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道，和一个氢的1s轨道的结合,在这里我们可以合并他们。

麻省理工公开课 - 化学原理课程节选

What about this second bond here sigma where we're going to have interaction of 2 p orbitals, is that sigma or pi?

那2p轨道相互作用的第二个键呢,它是，还是π？

麻省理工公开课 - 化学原理课程节选

So we can kind of flip it this way this will be one pi bond, this will be another interacting between these p orbitals.

我们可以把它这样翻一下,这是一个π键，这是另外一个p轨道之间,相互作用的π键。

麻省理工公开课 - 化学原理课程节选

All right, so if we think about b h bond here, again, it's the sigma bond, and we're going to say it's a boron 2 s p 2 hybrid orbital interacting with a hydrogen 1 s orbital.

这可以告诉我们，为什么它倾向于周围只有6个电子，好了，考虑一下这里的BH键,同样的，它是sigma键,我们说。

麻省理工公开课 - 化学原理课程节选

The reason that it's a sigma bond is sp3 because the s p 3 hybrid orbital is directly interacting with the 1 s orbital of the hydrogen atom, and that's going to happen on the internuclear axis, they're just coming together.

它是sigma键的原因,是因为,杂化轨道直接和氢原子1s轨道相互作用，它们作用发生在核间轴上，它们会到一起。

麻省理工公开课 - 化学原理课程节选

So it already should make sense why we have that p orbital there, in order to form a pi bond, we're going to need a p orbital.

这里有p轨道是很合理的,为什么我们在这里有P轨道，为了形成一个π键，我们需要一个p轨道。

麻省理工公开课 - 化学原理课程节选

There's not two bonds, that's one pi bond, and the reason is because it's 2 p orbitals coming together, and remember p orbitals have electron density above and below the axis, so when they come together, it kind of looks like one bonds, but essentially what we have here is one pi bond.

这不是两个键，这是一个π键，因为这是两个2p轨道组合而成的，记住p轨道在键轴之上,和键轴之下都有电子密度，当它们靠近时，这看着很像两个键，但本质上它是一个π键。

麻省理工公开课 - 化学原理课程节选

And again, this is between the p orbitals, these are not hybrid orbitals, so when we name this bond we're going to name it as a pi bond here, because it's between two p orbitals, and it's going to be between the carbon 2 p y orbital, and the other carbon 2 p y orbital.

同样，这是在p轨道之间的，它们不是杂化轨道，所以当我们命名这个键时,我们要命名它为π键，因为它在两个p轨道之间，而且是在碳2py轨道，和另一个碳2py轨道之间。

麻省理工公开课 - 化学原理课程节选

So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.

这就是苯环里的两种键，我们还剩一种，那就是这些p轨道之间，形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。

麻省理工公开课 - 化学原理课程节选

All right, so what we see here is we have our sigma bond that's along the internuclear axis here, but we also have a pi bond, because each of these atoms now has electrons in it's in a p orbital, so we're going to overlap of electron density above and below the bond.

这里我们看到sigma键,是沿着核间轴的，但我们还有一个π键，因为每个原子的p轨道上,都有电子，所以电子密度在键的上面,和下面都有电子密度交叠。

麻省理工公开课 - 化学原理课程节选