That means that p1 and -- where I am, the point number 1 and point number 2 were completely arbitrary.
因为1和,两个点是2,陆军上面。
Sorry, said that wrong, p1 radius 1 and angle 2, 2 radians is a little bit more than pi half.
而是半径和角度的表示,在这个例子中点,并不对应这个点,它实际上对应的是。
We start at p1, V1. and p external is equal to zero.
从状态开始,外部压强为零。
So they're going to P1, will the price of Firm 1, and P2 will be the price of Firm 2.
所以P1代表,公司1的价格,而P2代表公司2的价格
There is p1 sitting here, and all of the gas is sitting on that side of the plug.
所有的气体都在节流阀的这一边,在我们完成了实验之后。
So this guy here gets rid of this, and I have my answer as V1 over V2 to =p2/p1 the gamma power is equal to p2 over p1.
这两项抵消掉了,于是等式,变成了^γ
Each weighing, say, one 100th of the weight 1/100 needed to establish p external is equal to p1.
每颗重,比方说,使外压强,达到p1的重量的。
p1 But if I say, are p 1 and p 2 the same point, it says yes.
和p2是不是同一个点,It,says,no。,返回的结果是肯定的,在这里我有个要强调的点,这个例子里发生的是。
W2 If I go backwards, to work p1 becomes the negative from what I had p2 calculated before, so this becomes minus what I calculated before for w2.
应该是,总功等于,减去,等于。
p We want p equal to p external for the entire expansion, p2 and p external is decreased steadily from p1 to p2.
在膨胀过程中保持p等于外部,外部p很快从p1衰减到。
So now, instead of having p external p2 equals to p2 here, I put p1 and I let this whole thing go reversibly.
也就是说,现在开始的外界压强不是,而是p1,整个过程都是可逆的。
p2 It's taking the name p 1 and it's changing its value to point to exactly what p 2 points to.
我要把p1赋值为1,这个操作有什么用呢?,这个操作把p1这个名字的,指针的值改变让它。
w=p1v1 So we write down p1, V1.
我们写下。
You're pushing through here. p1 is greater than p2.
你们从这儿慢慢推动它。
Then I'm going to release these little pegs here and my piston is going to shoot up now p1 because p2 is less than p1.
现在移开插销,活塞就会往上冲,因为p2小于。
Wrev So minus w reversible, 1 p2 is less than p1, so p2 over p1 is less than one, log of something less than 1 is negative times negative.
那么,而p2小于p1,p2/p1小于,取对数后是负数,负负得正。
p2/p1 Then I'm going to get, be left with a p2 over p1.
于是右边剩下。
p1 V1 OK, so in my diagram now, I have p1, V1 for my gas.
于是可以画出现在的p-V图。
Then you take p1 to p2 with V constant.
图上画出来就是这样。
I take V1 to V2 first, keeping the pressure constant at p1, then I take p1 to p2 keeping the volume constant V2 at V2. Let's call this path 1.
容易计算的路径,第一条路径,是首先保持压强不变,体积从V1压缩到。
If p2, the pressure in p2, is less than the pressure in p1, is the gas going to want to go from p2 to p1 and the whole thing reverse back?
比p1中的压强小,在整个逆向过程中气体,会从p2到p1中去吗?
v1=/p1 So V2 = /p2, and V1 = /p1.
因此v2=/p2,同样地。
p2 p1 is greater than p2. Then I want to reverse direction of time. I want the arrow of time to go so that the gas goes from p2 to p1.
一直推,一直推,p1大于,接下来我想让时间倒流,让气体从p2到p1。p2比p1小。
I going to come back in a second to how it actually does that, but it basically says, get me x value for p 1, get me the x value for p 2, compare them, just as you would normally.
是一个类的实例,我要去取的这个实例,所关联的x值,我稍后会讲讲实际上,这里是怎么实现的,但是基本上它的意思就是,给我p1的x值。
V2 p1 times V2 minus V1. What that turns out to be, 0 this area right here. It's V1 minus V2 times p1.
第二步做的功是-pdV,积分从V2到,这部分积分出来是多少?应该是。
It's nR log of p2 over p1 for the process where there's a pressure change.
结果是dS等于nR乘以p2除以p1的对数,这是对压强变化的结果。
So on the p-V diagram, then, V1 V2 p1 p2 there's a V1 here a V2 here, a p1 here a p2 here.
在p-V图上,这是。
p1 So p2 is less than p1, the external pressures is less than the internal pressure.
抱歉,应该是p2小于,外界压强小于内部压强。
So any point I pick on that path will be equal to p1, V1 to the gamma.
也就是说路径上面任取一个点,计算p,V^γ
p1/p2 So, the nRT's cancel, and we have p1 over p2.
因此nRT相消,结果就是。
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