So if I try to rotate my 2 atoms, you see that I have to break that pi bond, because they need to be lined up so that the electron density can overlap.

如果我要试着转动两个原子，你会看到我必须要打破一个π键，因为他们需要连接起来,让那些电子能够重叠。

麻省理工公开课 - 化学原理课程节选

All right, so what we see here is we have our sigma bond that's along the internuclear axis here, but we also have a pi bond, because each of these atoms now has electrons in it's in a p orbital, so we're going to overlap of electron density above and below the bond.

这里我们看到sigma键,是沿着核间轴的，但我们还有一个π键，因为每个原子的p轨道上,都有电子，所以电子密度在键的上面,和下面都有电子密度交叠。

麻省理工公开课 - 化学原理课程节选