• "We believe strongly that there is no evidence to support any charge whatsoever and we would renew our request on behalf of these three young people and their families that the Iranian government exercise compassion and release them, so they can return home,"

    VOA: standard.2009.11.09

  • actually our third, but the second one we're going to talk about in terms of formal charge, which is thionyl chloride.

    实际上是第三个,但它是第二个,形式电荷的例子,也就是亚硫酰氯。

    麻省理工公开课 - 化学原理课程节选

  • Let's re-draw this, so it looks a little bit neater, where we have a triple bond in the middle instead, and again, we need our negative 1 charge there.

    让我们重写这个,这样看起来更整洁一点,我们有一个三键在中间,同样地,我们这里需要一个负电荷。

    麻省理工公开课 - 化学原理课程节选

  • And it does, so we know that we're probably on target in terms of calculating our formal charge.

    而它确实是这样,因此我们知道我们很有可能,算对了我们的形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • So, in this case, we see that our formal charge is negative on the nitrogen, in this case it's negative on oxygen.

    那么,在这种情况下,我们看到氮的形式电荷是负的,而在这种情况下,氧的是负的。

    麻省理工公开课 - 化学原理课程节选

  • And our eighth step in the process, again, is formal charge, which we will talk about very soon.

    而我们流程中的第八步,同样是,形式电荷,我们很快就会讨论它。

    麻省理工公开课 - 化学原理课程节选

  • For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.

    对于硫,我们从六个价电子开始,减去四个孤对电子,再减去二,算上我们的成键电子,因此最终我们有零个形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • So in our first structure, we would find for the nitrogen we have a formal charge 5 minus 4 minus 2, because we're starting with 5 valence electrons, so that is a formal charge of minus 1.

    那么在我们的第一个结构中,我们发现氮的形式电荷量是五减去四4,再减去二,因为我们开始有五个价电子,因此它的形式电荷量是负一。

    麻省理工公开课 - 化学原理课程节选

  • So if we have total +2 and complete shielding -1 where that can actually negate a full positive charge, because remember our nucleus is plus 2, +1 one of the electrons is minus 1, so if it totally blocks it, all we would have left from the nucleus is an effective charge of plus 1.

    抵消一个完全的正电荷,因为记住我们的原子核是,其中一个电子是,所以如果它完全挡住了它,我们从原子核中留下的,全部有效电荷就是,所以,在我们的第一个例子中,我们的第一种极端情况。

    麻省理工公开课 - 化学原理课程节选

  • If we go to the oxygen atom, now we're talking about starting with 6 in terms of valence electrons again, but instead of 2, you can see we have 6 lone pair electrons around the oxygen minus 1/2 of 2, so we have minus 1 is our formal charge.

    如果我们分析氧原子的话,现在我们讨论的还是,从六个价电子开始,但孤对电子不再是两个了,你会看到氧周围,有六个孤对电子,再减去二的一半,因此我们有一个负的形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • So, let's say we have an atomic number of 3, 3 that means we have 3 electrons, so we better hope to get our neutral atom that we have a charge of plus 3in the nucleus.

    这也是很合理的,因为Z就是原子序数,假设原子序数是,那就有3个电子,那我们就希望,性原子有个带3个正电荷的原子核。

    麻省理工公开课 - 化学原理课程节选

  • What we need to do is get rid of the Coulomb tag that we have - that's how we measure our electron charges - charge, and so we use this epsilon nought quite often, this permativity constant of a vacuum to make that conversion.

    怎么量度电子电荷,所以我们会经常用到,这个epsilon,nought记号,这是真空中的介电常数,我们还要指出,这个介电常数。

    麻省理工公开课 - 化学原理课程节选

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