So, what you see is near the nucleus, the density is the strongest, the dots are closest together.
你看在核子附近,密度非常高,这些点非常密。
At first it might be counter-intuitive because we know the probability density at the nucleus is the greatest.
起初我们觉得这和直观感觉很不相符,因为我们知道在原子核,出的概率密度是最高的。
Again, we have continuous electron density from one nucleus to the other.
再说一遍,原子核间有不间断的电子云,相接没有节点,没有空缺。
Because we know as we go to infinity, even though the density gets smaller and smaller and smaller, we still have electron density very far away from the nucleus.
因为我们知道即使到了无穷远处,尽管电子密度会变得非常非常非常小,但我们仍然有一定的电子密度,无论离原子核多远。
And so, the radial probability density at the nucleus is going to be zero, even though we know the probability density at the nucleus is very high, that's actually where is the highest.
所以径向概率密度,在核子处等于零,虽然我们知道在,核子处概率密度很大,实际上在这里是最大的,这是因为。
So what is actually going to matter is how closely that electron can penetrate to the nucleus, and what I mean by penetrate to the nucleus is is there probability density a decent amount that's very close to the nucleus.
所以实际上有关系的是,电子可以穿越至原子核有多近,我所指的穿越至原子核是,这里有一定数量的概率密度,可以距离原子核非常近。
The reason in our radial probability distributions we start -- the reason, if you look at the zero point on the radius that we start at zero is because we're multiplying the probability density by some volume, and when we're not anywhere 0 from the nucleus, that volume is defined as zero.
在径向概率密度里,我们开始,如果你们看半径的零点,我们从零点开始,因为我们用概率密,度乘以体积,而当我们,在离核子很近的地方,体积是,所以我们会在这里。
Because already I can see there is a line of sight from one nucleus to the other with no electron density whatsoever.
因为我已经看出在Z轴,有一条线从这个核到那个核,没有连续电子。
s And if we go ahead and superimpose the 3 s on top of the 3 p, you can see that the 3 s actually has some bit of probability density that gets even closer to the nucleus than the 3 p did.
如果我们继续将,重叠到3p上面,你们会看到3s事实上,有一点概率密度,距离原子核更近,比3p轨道。
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