So, from going from the shell of n equals 2, let's say, to the shell of n equals 3.
比如说,从n等于2到n,等于3壳层如何变化。
And so when we get to n equals three that would be m shell by the spectroscopists' notation.
当n等于3的时候,根据光谱学家的标记法,那就是第m层。
We're getting further away from the nucleus because we're jumping, for example, from the n equals 2 to the n equals 3 shell, or from the n equals 3 to the n equals 4 shell.
我们将会离原子核越来越远,因为我们在跃迁,比如从,n,等于,2,的壳层到n等于,3,的壳层,或者从,n,等于,3,的壳层到n等于,4,的壳层。
N so, we've got five electrons here in the valence shell.
是1s2,2s2,2p3,Nitrogen,is,1s2,,2s2,,2p3,因此,有5个价层电子。
Whatever the n number is, with the exception of helium, helium is the oddity because there's only two elements in n equals one shell.
无论n是多少,除了氦之外,氦是个特例,因为只有两个元素,在n为1的这一层。
We learn nothing from examining what is going on down here in n equals one shell.
必须仔细检查不然我们学不到什么的,这里n=1的壳。
This should make sense to you, because they don't, in fact, want to gain another electron, because that would mean that electron would have to go into a new value of n, a new shell, and that's really going to increase the energy of the system.
这对大家来说应该容易理解,因为它们实际上不想得到另一个电子,因为这意味着这个电子不得不,到一个新的,n,值更大的壳层上去,这将会增加系统的能量。
And when you talk about n for an orbital, it's talking about the shell that shell is kind of what you picture when you think of a classical picture of an atom where you have 1 energy level, the next one is further out, the next one's further away.
当你们谈到,某个轨道的n时,你们说的是壳层,壳层就是,你想象,一个原子,的经典图像时的场景,你有一个能级,下一个再更远的地方,再下一个又更远。
So there are two electron configurations in the n equals one shell, if we follow according to the selection rules that we spelled out last day.
如果根据上次课,我们阐明的原子光谱选择定则,我们就会知道在n等于1的那一层,有两种电子图像构型。
And, if we go to n equals two, this would be the l shell.
而当n等于2时,也就是L层。
Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.
芯电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子。
That's associated with one, n equals one, inner shell.
它和1紧密联系,n等于1,在内层时。
And we can generalize to figure out, based on any principle quantum number n, how many orbitals we have of the same energy, n and what we can say is that for any shell n, there are n squared degenerate orbitals.
我们可以总结出来,在,主量子数为n的情况下,同一个能量上,有多少个轨道,我们可以说,对任何壳层,有n平方个简并轨道。
The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.
我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。
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