That energy will be absorbed by the hydrogen atom, n=1 the electron will rise from n equals one n=2 to n equals two.
这能量将会被氢原子吸收,这个电子会从,上升到。
So another way to say that is, in a sense, if we're thinking about the excited state of a hydrogen atom, the first excited state, or the n equals 2 state, what we're saying is that it's actually bigger than the ground state, or the 1 s state of a hydrogen atom.
换句话说,如果我们激发一个氢原子,第一激发态或者说n等于2的态,我们说它比氢原子基态,或者说1s态要大。
n l m s Once we have chosen a certain mix of n, l, m and s, it is used once for that particular atom.
一旦我们选定了一组量子数,它就只能被一个固定原子所有。
And I want to really highlight here we're talking about for a hydrogen atom orbitals - with the same n value have the same energy.
我想强调的是,我们所说的,都是对单个的氢原子,和言的,对于同样的n值能量相同。
We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.
我们以后会讲到,更加复杂的情况,那时候,不只有一个原子,但当我们讲,单个原子的时候,我们知道结合能,等于,负的Rydberg常数,除以n平方,所以它仅仅由n决定的。
But there's something you'll note here also when I point out the case of the 2 s versus the 2 p, which is what I mentioned that I would be saying again and again, which is when we look at the hydrogen atom, the energy of all of the n equals 2 orbitals are exactly the same.
但是这里有一些事情你们也会注意到,当我指出2s和2p的情况,我之前提过,我会一次又一次的说,我们在观察氢原子的时候,2层轨道的所有n的能量,是完全相同的。
So, that also tells us that the n minus ion is less stable than the neutral atom itself.
而且,这还告诉我们,负一价的氮离子不如中性氮原子稳定。
So what we'll do is this problem here, which is let's calculate out what the wavelength of radiation n would be emitted from a hydrogen atom if we start at the n equals 3 level and we go down to the n equals 2 level.
我们来做这个问题,让我们来计算一下,从n等于3到,等于2能级氢原子辐射的波长是多少。
So, if, for example, we were looking at a hydrogen atom in the case where we have the n equals 1 state, so the electron is in that ground state, the ionization energy, it makes sense, is going to be the difference between the ground state and the energy it takes to be a free electron.
电离氢原子所需要的能量,如果我们看n等于1的情况,电子在基态,那电离能,很合理的就是基态,和自由电子态的能量差。
So, why don't you go ahead and tell me, keeping that in mind, which atom in terms of h c or n would you expect to be in the center of hydrogen cyanide?
那么,请大家来告诉我,并且记住它,你认为氢,碳和氮中哪个原子,应该在氰化氢的中间呢?
That's why in the earlier models of the atom, they're not horrible to sometimes think about just each n value as a little ring around.
这就是为什么在早期原子模型中,人们没有感觉到把每一个,n,都想象成,一个绕核的小圆圈有什么不妥。
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