• So, the first thing we do is put two electrons between h and c, and then two electrons between c and n.

    那么,我们先在氢和碳之间放两个电子,然后在碳和氮之间再放两个电子

    麻省理工公开课 - 化学原理课程节选

  • And we know that n describes the total energy, that total binding energy of the electron, so the total energy is going to be equal to potential energy plus kinetic energy.

    我们知道,n是描述总能量的,电子总的结合能,所以总能量,等于,势能加动能。

    麻省理工公开课 - 化学原理课程节选

  • And if that is the energy to go from n equals one n=2 this is the amount of energy that has to be left as kinetic energy of the electron.

    如果这个能量是从n=1到,然后,to,n,equals,two,then,这些能量,会作为电子的动能,被消耗掉。

    麻省理工公开课 - 固态化学导论课程节选

  • So if we say that l is just talking about our kinetic energy part, our rotational kinetic energy, and we know that electrons have potential energy, then it makes sense that l, in fact, can never go higher than n.

    如果我们说,l仅仅是,描述动能项,我们的旋转动能,我们知道,电子有势能,所以可以理解,l不能比n高。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense to you, because they don't, in fact, want to gain another electron, because that would mean that electron would have to go into a new value of n, a new shell, and that's really going to increase the energy of the system.

    这对大家来说应该容易理解,因为它们实际上不想得到另一个电子,因为这意味着这个电子不得不,到一个新的,n,值更大的壳层上去,这将会增加系统的能量。

    麻省理工公开课 - 化学原理课程节选

  • And, in fact, it can't even reach n, because then we would have no potential energy at all in our electron, which is not correct.

    事实上,它连n都达不到,因为如果那样的话,电子就没有势能了,这是不可能的。

    麻省理工公开课 - 化学原理课程节选

  • So there are two electron configurations in the n equals one shell, if we follow according to the selection rules that we spelled out last day.

    如果根据上次课,我们阐明的原子光谱选择定则,我们就会知道在n等于1的那一层,有两种电子图像构型。

    麻省理工公开课 - 固态化学导论课程节选

  • We know that the orbitals for multi-electron atoms depend both on n and on l.

    我们知道对于多电子原子轨道,是依赖于n和l的。

    麻省理工公开课 - 化学原理课程节选

  • Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.

    电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子

    麻省理工公开课 - 化学原理课程节选

  • So, if, for example, we were looking at a hydrogen atom in the case where we have the n equals 1 state, so the electron is in that ground state, the ionization energy, it makes sense, is going to be the difference between the ground state and the energy it takes to be a free electron.

    电离氢原子所需要的能量,如果我们看n等于1的情况,电子在基态,那电离能,很合理的就是基态,和自由电子态的能量差。

    麻省理工公开课 - 化学原理课程节选

  • I think most and you are familiar with the Aufbau or the building up principle, you probably have seen it quite a bit in high school, and this is the idea that we're filling up our energy states, again, which depend on both n and l, one electron at a time starting with that lowest energy and then working our way up into higher and higher orbitals.

    我认为你们大多数熟悉奥弗堡,或者构建原理,你们可能,在高中见过它,又一次,这是我们填充能级的观点,与n和l有关,一个电子每次从,最低的能级开始,然后以我们的方式上升到,更高更高的轨道。

    麻省理工公开课 - 化学原理课程节选

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