So, let's think of the energy of interaction when we're comparing atomic orbitals to molecular bonding orbitals.

当我们比较原子轨道和分子轨道的时候,我们来考虑一下相互作用能。

麻省理工公开课 - 化学原理课程节选

And so this lower level is called a bonding orbital, and it is a bonding molecular orbital.

所以能级较低的轨道叫做成键轨道，这就是成键分子轨道。

麻省理工公开课 - 固态化学导论课程节选

So, we'll start today talking about the two kinds of molecular orbitals, we can talk about bonding or anti-bonding orbitals.

今天我们先来,讨论两种分子轨道，我们要讨论成键和反键轨道。

麻省理工公开课 - 化学原理课程节选

Now if you read in the book, you read about where this figure is shown in the book, you can understand more about why these structures line up in the right way so that the right molecular elements are together to form hydrogen bonding pairs between them.

如果你预习过课本,课本中有关于这些详细的描述,你可以更深刻的理解,为什么这些结构是采用这种连接方式,以使对应的分子部分靠近,并形成氢键连接

耶鲁公开课 - 生物医学工程探索课程节选

So specifically, what we do associate them instead is within molecular orbitals, and what we say is that they can be either in bonding or anti-bonding orbitals.

特别的，我们把它们和,分子轨道相联系起来，我们说它们可以成为,成键轨道或者反键轨道。

麻省理工公开课 - 化学原理课程节选

You might have thought before we started talking about molecular orbital theory that non-bonding was the opposite of bonding, it's not, anti-bonding is the opposite of bonding, and anti-bonding is not non-bonding.

你也许在我们讨论分子轨道之前,就想过非成键时成键的反面，它不是，反键才是成键的反面，反键不是非成键。

麻省理工公开课 - 化学原理课程节选

So if we name this orbital, this is an anti-bonding molecular orbital So we had bonding and now we're talking about anti-bonding.

这是反键分子轨道,我们有了成键，现在我们讨论反键。

麻省理工公开课 - 化学原理课程节选

I want to finish this discussion by including the anti-bonding orbital, and this is a tip for you when you're drawing your molecular orbital diagrams, any time you draw a bonding orbital, there is also an anti-bonding orbital that exists.

我想要以包含反键轨道,来结束这个讨论，告诉你们一个,画分子轨道图的小技巧，任何时候你画一个成键轨道，都会存在一个反键轨道。

麻省理工公开课 - 化学原理课程节选

So we'll start to look at molecules and we'll see if we take two atoms and we fill in our molecular orbital and it turns out that they have more anti-bonding orbitals than bonding, that's -- a diatomic molecule we'll never see.

我们要看开始看一看分子,并且我们会发现如果我们,取两个原子并且填入分子轨道,结果是它们的反键轨道,比成键轨道更多，这就是-一个我们不会看到的二元子分子。

麻省理工公开课 - 化学原理课程节选

So we're going to finish talking about molecular orbital theory, we'll switch over to discussing bonding in larger molecules, even larger than diatomic, so we'll move on to talking about valence bond theory and hybridization.

我们要结束关于分子轨道理论的讨论，转向讨论大分子的成键，比二原子分子更大的分子，我们会继续讨论价电子成键理论,和杂化。

麻省理工公开课 - 化学原理课程节选

So that's the idea of a bonding molecular orbital.

这就是成键分子轨道的概念。

麻省理工公开课 - 化学原理课程节选

So we have two electrons in our bonding orbital, but because we use the same rules to fill up molecular orbitals as we do atomic orbitals, so the Pauli exclusion principle tells us we can't have more than two electrons per orbital, so we have to go up to our anti-bonding orbital here.

所以在成键轨道上有两个电子，但因为我们用了和原子轨道时,用的相同的规则，所以Pauli不相容原理告诉我们,一个轨道上不能有两个以上的电子，所以我们需要填充到反键轨道上去。

麻省理工公开课 - 化学原理课程节选