For an angular node, we're just talking about what the l value is, so whatever l is equal to is equal to the number of angular nodes you have.
对于角向节点,我们其实就是在讨论l,的值是多少,因此不管,l,的值等于几,它就等于你所有的角向节点的数目。
So if we say that we have a 2 p orbital here, that means that we can have 2 how many different complete orbitals have a 2 for an n, and a p as its l value? three.
如果我们说这里有一个“2p“轨道,那就意味着我们有,多少完全不同的轨道对于n有一个,而且对于l值有一个p?3个。
It says, right. If j is-- well it says until j is at the less than the length of l-- it says, if min value is bigger than the thing I'm looking at I'm going to do something, all right?
只要j比长度l小,如果MinVal比我要找到元素大,我就要做些什么了,我们来遍历?
So if we're keeping n the same, we look and what we saw was that size actually decreases as we increase the value of l.
如果我们保持n不变,我们看到随着l值的,增大尺寸变小。
PROFESSOR: OK. We can have n 4, l 3, and then, sure, we can have m sub l equal negative 2 if l equals 3 What's the second value of l that we can have?
教授:嗯,我们有n4,l3,然后我们有ml等于-2,如果l等于3,l可以有的第二个值是多少?
If we have n equals 4, what is the highest value of l that we can have?
如果n等于4,l的最大值是多少?
So, if we think of just an example, 2 we could say that 4 l equals 2, what would be our lowest value of m sub l?
举个例子,如果我们说l等于,那m小标l,最小值是多少?
So when we talk about p orbitals, it's similar to talking about s orbitals, and the difference lies, and now we have a different value for l, so l equals 1 for a p orbital, and we know if we have l equal 1, we can have three different total orbitals that have sub-shell of l equalling 1.
当我们考虑p轨道时,这和s轨道的情形和相似,不同之处在于l的值不一样,对于p轨道,l等于1,我们知道如果l等于1,我们有3个,不同的轨道。
And unlike n, l can start all the way down at 0, and it increases by integer value, so we go 1, 2, 3, and all the way up.
不像n,l可以从0开始取,然后每次增加一个整数,所以我们可以去1,2,3,一直下去。
So, our next level up that we can go is going to be the n equals 2 energy level, but we also have an l and an m value, 0 so our lowest l is going to be a there.
所以下一个能量,是n等于2的能级,但我们还有l和m的值,所以我们最低的l等于。
But also unlike n, l cannot have just any value, we can't go into infinity.
但不像n,l,不能取所有整数,不能到正无穷。
Again, the reason for that is because the energy only depends on the n value here, it doesn't depend on l or on m.
因为,能量,只和n的值有关,与l和m的值无关。
The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.
我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。
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