• For an angular node, we're just talking about what the l value is, so whatever l is equal to is equal to the number of angular nodes you have.

    对于角向节点,我们其实就是在讨论l,的值是多少,因此不管,l,的值等于几,它就等于你所有的角向节点的数目。

    麻省理工公开课 - 化学原理课程节选

  • So if we say that we have a 2 p orbital here, that means that we can have 2 how many different complete orbitals have a 2 for an n, and a p as its l value? three.

    如果我们说这里有一个“2p“轨道,那就意味着我们有,多少完全不同的轨道对于n有一个,而且对于l值有一个p?3个。

    麻省理工公开课 - 化学原理课程节选

  • It says, right. If j is-- well it says until j is at the less than the length of l-- it says, if min value is bigger than the thing I'm looking at I'm going to do something, all right?

    只要j比长度l小,如果MinVal比我要找到元素大,我就要做些什么了,我们来遍历?

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • So if we're keeping n the same, we look and what we saw was that size actually decreases as we increase the value of l.

    如果我们保持n不变,我们看到随着l值的,增大尺寸变小。

    麻省理工公开课 - 化学原理课程节选

  • PROFESSOR: OK. We can have n 4, l 3, and then, sure, we can have m sub l equal negative 2 if l equals 3 What's the second value of l that we can have?

    教授:嗯,我们有n4,l3,然后我们有ml等于-2,如果l等于3,l可以有的第二个值是多少?

    麻省理工公开课 - 化学原理课程节选

  • If we have n equals 4, what is the highest value of l that we can have?

    如果n等于4,l的最大值是多少?

    麻省理工公开课 - 化学原理课程节选

  • So, if we think of just an example, 2 we could say that 4 l equals 2, what would be our lowest value of m sub l?

    举个例子,如果我们说l等于,那m小标l,最小值是多少?

    麻省理工公开课 - 化学原理课程节选

  • So when we talk about p orbitals, it's similar to talking about s orbitals, and the difference lies, and now we have a different value for l, so l equals 1 for a p orbital, and we know if we have l equal 1, we can have three different total orbitals that have sub-shell of l equalling 1.

    当我们考虑p轨道时,这和s轨道的情形和相似,不同之处在于l的值不一样,对于p轨道,l等于1,我们知道如果l等于1,我们有3个,不同的轨道。

    麻省理工公开课 - 化学原理课程节选

  • And unlike n, l can start all the way down at 0, and it increases by integer value, so we go 1, 2, 3, and all the way up.

    不像n,l可以从0开始取,然后每次增加一个整数,所以我们可以去1,2,3,一直下去。

    麻省理工公开课 - 化学原理课程节选

  • So, our next level up that we can go is going to be the n equals 2 energy level, but we also have an l and an m value, 0 so our lowest l is going to be a there.

    所以下一个能量,是n等于2的能级,但我们还有l和m的值,所以我们最低的l等于。

    麻省理工公开课 - 化学原理课程节选

  • But also unlike n, l cannot have just any value, we can't go into infinity.

    但不像n,l,不能取所有整数,不能到正无穷。

    麻省理工公开课 - 化学原理课程节选

  • Again, the reason for that is because the energy only depends on the n value here, it doesn't depend on l or on m.

    因为,能量,只和n的值有关,与l和m的值无关。

    麻省理工公开课 - 化学原理课程节选

  • The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

    我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

    麻省理工公开课 - 化学原理课程节选

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