He once belonged to the L.D.P.

VOA: special.2009.09.05

And what I want to point out here is this angular dependence for the p orbitals for the l equals 1 orbital.

这里我要指出的是,ｌ等于１的ｐ轨道随角度的变化。

麻省理工公开课 - 化学原理课程节选

So that's why we saw, for example, in the p orbitals we had one angular node in each p orbital, because l is equal to 1 there.

这就是为什么在ｐ轨道中,每个轨道节点数都是１,因为这里ｌ等于１．

麻省理工公开课 - 化学原理课程节选

So if we compare l increasing here, so a 3 s to a 3 p to a 3 d, what we find is that it's only in the s orbital that we have a significant probability of actually getting very close to the nucleus.

我们比较当ｌ变大的时候，从３ｓ到３ｐ到３ｄ,我们可以发现只有ｓ轨道,有很大的概率,非常接近原子核。

麻省理工公开课 - 化学原理课程节选

In contrast when we're looking at a p orbital, so any time l is equal to 1, and you look at angular part of the wave function here, what you see is the wave function either depends on theta or is dependent on both theta and phi.

相反当我们看ｐ轨道时，任何时候ｌ等于１,你们看它的角向波函数，你们可以看到它要么是和theta有关,要么是和theta和phi都有关。

麻省理工公开课 - 化学原理课程节选

So it's OK to not specify. I want to point out, pz whether you're in the p x, the p y, or the p z, unless a question specifically m asks you to specify the m sub l, which occasionally will happen, but if it doesn't happen you just write it like this.

我想指出的是，无论你在px，py或，除非一个问题特别地,让你指出l下面的，这种情况有时会发生，这样就可以了,但是如果它不做要求你们写成。

麻省理工公开课 - 化学原理课程节选