The people who started the company named it Google because in mathematics, googol,spelled g-o-o-g-o-l, is an extremely large number.
VOA: special.2009.04.19
And s is this lowercase notation l that the spectroscopists use in place of the l number.
而s这个小写字母,被光谱学家用来代替数字。
The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.
我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。
And this spin magnetic quantum number we abbreviate as m sub s, so that's to differentiate from m sub l.
这个自旋磁量子数我们把它简写成m下标s,以和m小标l有所区分。
And we can calculate that with the formula that we used, which was just n minus l minus 1 equals the number of nodes.
这个我们可以用我们以前用过的那个公式来计算,也就是节点数等于n减去l减去1
The other thing that we took note as is what happens as l increases, and specifically as l increases for any given the principle quantum number.
另外一个我们要注意的是,l增加时如何变化,特别是对于某个给定的,主量子数l变化时如何变化。
We didn't just need that n, not just the principle quantum number that we needed to discuss the energy, but we also need to talk about l and m, as we did in our clicker question up here.
我们不仅需要n,不仅要这个可以,决定能量的主量子数,还需要m和l,就像我们做这道题这样。
No, we can't. Because if l equals 1, we can not have m sub l equal negative 2, right, because the magnetic quantum number only goes from negative l to positive l here.
不行,因为如果l等于1,ml的值不可能等于-2,对吧,因为磁量子数的值,这时只能从-1到1
And when we talk about angular nodes, the number of angular nodes we have in an orbital is going to be equal to l.
当我们谈到角向节点时,一个轨道的,角向节点数等于l
And the first is l, and l is angular momentum quantum number, and it's called that because it dictates the angular momentum that our electron has in our atom.
第一个就是l,l是,角动量量子数,叫它这个名字,是因为它表明,原子中,电子的角动量是多少。
For an angular node, we're just talking about what the l value is, so whatever l is equal to is equal to the number of angular nodes you have.
对于角向节点,我们其实就是在讨论l,的值是多少,因此不管,l,的值等于几,它就等于你所有的角向节点的数目。
And when we talk about l it is a quantum number, so because it's a quantum number, we know that it can only have discreet values, it can't just be any value we want, it's very specific values.
当我们讲,l是一个量子数时,因为它是量子数,我们知道,它只能去分立的值,它不能取到所有的数,它取一些确定的数。
And that's just to take 1 the principle quantum number l and subtract it by 1, and then also subtract from that your l quantum number.
主量子数,减去,再减去,量子数,你们可以对1s轨道来验证一下。
l So, if we're talking about a 4 p orbital, and our equation is n minus 1 minus l, the principle quantum number is 1 4, 1 is 1 -- what is l for a p orbital?
我们方程是n减去1减去,主量子数是,4,1是1,--p轨道的l是多少?,学生:
For an f orbital, what is the quantum number l equal to?
对于一个,f,轨道,它的角量子数,l,等于几?
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