• In contrast, if we're taking the wave function and describing it in terms of n, l, m sub l, and now also, the spin, what are we describing here?

    相反,如果我们考虑一个波函数,然后用n,l,m小标l,还有自旋,我们描述的是什么?

    麻省理工公开课 - 化学原理课程节选

  • So, first, if I point out when l equals 0, when we have an s orbital, what you see is that angular part of the wave function is equal to a constant.

    首先,如果l等于0,那就是s轨道,你们可以看到,它波函数的角度部分是一个常数。

    麻省理工公开课 - 化学原理课程节选

  • It turns out there's a new function strlen S-T-R-L-E-N that you probably have not used yet called strlen, S-T-R-L-E-N, programmers early on and still like to be succinct but communicates sufficiently what they mean.

    结果这里有个新的函数,你可能没有使用过,叫做,早期的和现在的程序员喜欢简洁地,但是能充分的传达他们的意思。

    哈佛公开课 - 计算机科学课程节选

  • s We are back over to E as a function of n, l, m and s, only we got there through this other torturous route.

    我们回到将E作为函数n,l和,只要我们解决了这个烦人的路径。

    麻省理工公开课 - 固态化学导论课程节选

  • R And we abbreviate that by calling it r, l by two quantum numbers, and an l as a function of little r, radius.

    我们把它简称为,两个指定的量子数n和,它是半径小r的函数。

    麻省理工公开课 - 化学原理课程节选

  • So let's just think exactly what this means, and that means that if we take away function and we define it in terms of n, l and m sub l, what we're defining here is the complete description of an orbital.

    让我们来考虑一下这是什么意思,这是说如果我们不考虑波函数,而是用n,l,m下标l来定义它,我们定义的,是一个轨道的完整描述。

    麻省理工公开课 - 化学原理课程节选

  • n l So negative e, which is sub n l, because it's a function of n and l in terms of quantum numbers.

    也就是负的,E,下标是,因为它是一个,关于量子数,n,和,l,的函数。

    麻省理工公开课 - 化学原理课程节选

  • So when we talk about a wave function squared, n l m he wave function, any one that we specify between n, l and m, at any position that we specify based on r, theta, and phi.

    一个波函数,的平方时,对特定,特定位置r,theta,phi波函数,取平方,如果我们取平方。

    麻省理工公开课 - 化学原理课程节选

  • In contrast when we're looking at a p orbital, so any time l is equal to 1, and you look at angular part of the wave function here, what you see is the wave function either depends on theta or is dependent on both theta and phi.

    相反当我们看p轨道时,任何时候l等于1,你们看它的角向波函数,你们可以看到它要么是和theta有关,要么是和theta和phi都有关。

    麻省理工公开课 - 化学原理课程节选

  • l But now we need to talk about l and m as well. So now when we talk about a ground state in terms of wave function, we need to talk about the wave function of 1, 0, 0, and again, as a function of r, theta and phi.

    但我们现在需要讨论,和m,现在当我们讨论,波函数的基态时,我们讨论的,是1,0,0的波函数,同样的,它也是r,theta和phi的函数。

    麻省理工公开课 - 化学原理课程节选

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