So what that means is that we're limited in any atom to having two electrons per orbital, right, because for any orbital we can either have a spin up electron, a spin down electron, or both.

这意味着在一个原子内,每个轨道上可以有两个电子，对吧，因为对任何轨道,我们可以有自旋向上或者自选向下或者两者都有。

麻省理工公开课 - 化学原理课程节选

So, you can see how this can directly give us different ionization energies for any atom that we're interested in studying.

那么，大家可以理解,这种技术如何直接给出我们所要研究的,任何一种原子的所有不同的电离能。

麻省理工公开课 - 化学原理课程节选

But, in fact, we can also talk about the ionization energy of different states of the hydrogen atom or of any atom.

但实际上我们也可以讨论氢原子,或者其它任何原子的其它能级的电离能。

麻省理工公开课 - 化学原理课程节选

And what we can do is we can also use the Schrodinger equation to make these accurate predictions for any other atom that we want to talk about in the periodic table.

我们能做的是,我们可以使用,薛定谔方程去做一些,关于我们想要讨论的元素周期表,中任何一个原子的预测。

麻省理工公开课 - 化学原理课程节选

So now we can go back and think about filling in these electron configurations for any atom.

实用现在我们返回来再考虑,关于填充任意原子,电子构型的问题。

麻省理工公开课 - 化学原理课程节选

So, what this lets us do now is directly compare, for example, the strength of a bond in terms of a hydrogen atom and hydrogen molecule, compared to any kind of molecule that we want to graph on top of it.

因此，这让我们现在可以做到直接进行比较，比如，将一个氢原子，和一个氢分子的键的强度，与任何其它类型的分子进行比较,我们只需要把它的曲线也画在这幅图上。

麻省理工公开课 - 化学原理课程节选

z So the main idea here is z effective is not z, so don't try to plug one in for the other, they're absolutely different quantities in any case when we're not talking about a 1 electron atom.

所以这里主要的观点是有效的z不同于，所以不要尝试将一个插入到另一个，当我们不在讨论1个电子的原子时,它们在任何情况下是绝对不同的量子数。

麻省理工公开课 - 化学原理课程节选

So, essentially when we're talking about these equations up here, all we're doing is talking about the regular Rydberg formulas, but instead we could go back and re-derive the equation for any one electron atom, which would just mean that we put that z squared term in the front.

所以本质上,当我们讨论，这些问题时，我们说的是常规的，Rydberg公式，但对任何其他单电子原子，我们不用,从头再推到，而是仅仅把，z平方项放在前面。

麻省理工公开课 - 化学原理课程节选