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And now we're almost done, except what we H really want is delta H and not delta U, right.
我们差不多已经完成了,除了我们实际上想要的是Δ
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So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.
它们的能量实际上,比对应的氢,原子轨道要低。
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How do we go from that experiment to H the terms that we're trying to get, these slopes.
我们怎样从实验得到我们想要的量？,记住，我们想要得到Δ
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stdio c So somewhere there's standard IO dot C, stdio h somewhere they're standard IO dot H, but, for me, right now, the only file I need to know about is the dot H, -- because what Sharp include really does -- it's what's called a preprocessor directive.
所以某个地方有一个，现在对于我来说它们是，我只要知道那个，h文件，因为Sharp包含的-,叫做预处理指令。
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And we give different names, depending on what kind of electrons we're dealing with, so, for example, with h c l here, we can talk about having bonded versus lone pair electrons.
我们还起了不同的名字，给我们要处理的不同类型的电子，以氯化氢为例，我们来介绍一下成键电子与孤对电子。
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And if you put this in the well-ventilated area, if you prepare this outside, the h c n gas will actually be released into the air, so you're safe, you can eat it later.
而如果你把它们放在通风良好的地方，在室外处理，那么氰化氢气体,将会被释放到空气中，这样你就安全了，过后就可以吃了。
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So, for example, down here I wrote that it was n 2 and that it was h 2, but when I re-wrote the molecules up here, you saw that it's an h h single bond where it's a nitrogen-nitrogen triple bond.
比如，在这下面我写的是氮分子2,而这个是氢分子，但我在上面把这些分子的形式改写了，大家可以看到,这是一个氢与氢之间的单键，含一个氮与氮之间的三键。
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The other thing is that we can re-write our h c n in terms of bonds.
还有一件事是我们可以用键的形式来表示氰化氢。
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So in terms of thinking about ethane, we actually have two bond types that we're going to be describing just in terms of the carbon-carbon bond and then the carbon h bonds.
对于乙烷，我们有两种键,我们继续讨论一下,碳碳键,和碳氢键。
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So, if we talk about dissociating h 2, we're going from the h 2 molecule, and breaking this bond right in half, so we now have two individual hydrogen atoms here.
那么，如果我们讨论的是离解氢分子，我们将从氢分子开始，使这个键断裂，一分为二，那么就得到了两个分开的氢原子。
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So it helps us predict, will we see this, for example, h 2, which we're going to be about to do, we'll see is stabilized because it has more bonding than anti-bonding.
这帮助我们预测，我们等会会看到，比如H2O，我们等会要讲到，我们会看到它更稳定是,因为成键比反键更多。
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Of course, they're all sorts of conditions under which a reaction could be wrong in the lab or outdoors or however, right. But this is the way we're going to define delta H of reaction.
当然，在实验室或室外,之类的环境中，在这些条件下,反应可能出错，但这是我们,要定义反应的△H的方法。
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So instead of being equal to negative z squared, now we're equal to negative z effective squared times r h all over n squared.
这里不再等于-z的平方，现在我们等于-有效的z的平方,乘以RH除以n的平方。
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All right, so if we think about b h bond here, again, it's the sigma bond, and we're going to say it's a boron 2 s p 2 hybrid orbital interacting with a hydrogen 1 s orbital.
这可以告诉我们，为什么它倾向于周围只有6个电子，好了，考虑一下这里的BH键,同样的，它是sigma键,我们说。
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So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.
我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来，我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。
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T Remember, we're trying to get delta H, p we're trying to get dH/dT constant pressure and dH/dp constant temperature. OK, these are the two things were trying to get here.
想要得到在恒压状态下的偏H偏，和在恒温状态下的偏H偏,好的，这是两个我们，在这里想要得到的东西。
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So if you had a high temperature, this a small compared to b. If you're negative which means that dT/dp at constant H is less than zero.
高于反转温度，这一项相比于b很小,意味着H恒定时,偏T偏p小于零。
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The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.
我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候，如果你们看,波函数，的角向部分，你们会发现它是一个常数。
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