So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.
它们的能量实际上,比对应的氢,原子轨道要低。
So, why don't you go ahead and tell me, keeping that in mind, which atom in terms of h c or n would you expect to be in the center of hydrogen cyanide?
那么,请大家来告诉我,并且记住它,你认为氢,碳和氮中哪个原子,应该在氰化氢的中间呢?
All right, so the type of bond energies that we can go and look up in tables are individual atom bonds, H-H, F-F, and the like.
好的,键能的类型,我们能够在表中查到,都是独立的原子键,H-H,F-F以及类似的。
So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.
那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。
H2 So the simplest case we can think of is with h 2 where we have two unpaired electrons, each in a 1 s orbital of a separate h atom.
最容易想到的例子是2,我们有两个未配对电子,每个都在一个分开的1s轨道上。
The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.
我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候,如果你们看,波函数,的角向部分,你们会发现它是一个常数。
What I want to point out also is that this h hat, the Hamiltonian operator written out for the simplest case we can even imagine, which is a hydrogen atom where we only have one electron that we're dealing with, and of course, one nucleus.
我也想指出的是,我们能想到的最简单情况,的哈密顿算符,是一个只有一个电子,也只有一个原子核的氢原子。
And in doing that, we'll also talk about the shapes of h atom wave functions, specifically the shapes of orbitals, and then radial probability distribution, which will make sense when we get to it.
为了这样做,我们要讲一讲,氢原子,波函数的形状,特别是轨道的形状,然后要讲到径向概率分布,当我们讲到它时,你们更能理解。
So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.
那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。
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