• So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.

    它们的能量实际上,比对应的氢,原子轨道要低。

    麻省理工公开课 - 化学原理课程节选

  • So, why don't you go ahead and tell me, keeping that in mind, which atom in terms of h c or n would you expect to be in the center of hydrogen cyanide?

    那么,请大家来告诉我,并且记住它,你认为氢,碳和氮中哪个原子,应该在氰化氢的中间呢?

    麻省理工公开课 - 化学原理课程节选

  • All right, so the type of bond energies that we can go and look up in tables are individual atom bonds, H-H, F-F, and the like.

    好的,键能的类型,我们能够在表中查到,都是独立的原子键,H-H,F-F以及类似的。

    麻省理工公开课 - 固态化学导论课程节选

  • So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.

    那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。

    麻省理工公开课 - 化学原理课程节选

  • H2 So the simplest case we can think of is with h 2 where we have two unpaired electrons, each in a 1 s orbital of a separate h atom.

    最容易想到的例子是2,我们有两个未配对电子,每个都在一个分开的1s轨道上。

    麻省理工公开课 - 化学原理课程节选

  • The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.

    我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候,如果你们看,波函数,的角向部分,你们会发现它是一个常数。

    麻省理工公开课 - 化学原理课程节选

  • What I want to point out also is that this h hat, the Hamiltonian operator written out for the simplest case we can even imagine, which is a hydrogen atom where we only have one electron that we're dealing with, and of course, one nucleus.

    我也想指出的是,我们能想到的最简单情况,的哈密顿算符,是一个只有一个电子,也只有一个原子核的氢原子。

    麻省理工公开课 - 化学原理课程节选

  • And in doing that, we'll also talk about the shapes of h atom wave functions, specifically the shapes of orbitals, and then radial probability distribution, which will make sense when we get to it.

    为了这样做,我们要讲一讲,氢原子,波函数的形状,特别是轨道的形状,然后要讲到径向概率分布,当我们讲到它时,你们更能理解。

    麻省理工公开课 - 化学原理课程节选

  • So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.

    那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。

    麻省理工公开课 - 化学原理课程节选

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