But still, when we're talking about the radial probability distribution, what we actually want to think about is what's the probability of finding the electron in that shell?
但当我们讲到径向概率分布时,我们想做的是考虑,在某一个壳层里,找到电子的概率,就把它想成是蛋壳?
And when we do that we can see this curve, this probability curve, where we have a maximum probability of finding the electron this far away from the nucleus.
当我们这样做时,我们可以看到这个曲线,这个概率分布曲线,这里有发现,电子的最大概率。
And this is proportional to the probability of finding an electron.
它和观察的电子云概率,成正比关系。
And when we take the wave function and square it, that's going to be equal to the probability density of finding an electron at some point in your atom.
当我们把波函数平方时,就等于在某处,找到一个电子的概率密度。
We can not do that with quantum mechanics, the more true picture is the best we can get to is talk about what the probability is of finding the electron at any given nucleus.
在量子力学里我们不这样做,我们能得到的更加真实的图像,是关于在某处,找到电子的概率。
But what we're saying is there's a node here, so that there's no probability of finding an electron between those two points.
但我们说在节点这里,这两点是,不可能发现电子的。
Anywhere where that's the case we're going to have no probability density of finding an electron.
这时面内任何地方,找到电子的概率密度都是零。
The answer is, in fact, there is zero, absolutely zero probability of finding a electron here.
实际上它在这里是为零的,在这里找到电子的概率严格等于零。
And if we go ahead and square that, then what we get is a probability density, and specifically it's the probability of finding an electron in a certain small defined volume away from the nucleus.
我们得到的是,一个概率密度,它是,在核子周围,某个很小的,特定区域,找到电子的概率,所以它是概率密度。
Probability density of finding an electron within that molecule in some given volume.
在分子内某空间找到,一个电子的概率密度。
This is the point at which your probability is highest for finding an electron.
电子概率,最大的地方,对于氢原子。
So if we take this term, which is a volume term, and multiply it by probability over volume, what we're going to end up with is an actual probability of finding our electron at that distance, r, from the nucleus.
如果我们取这项,也就是体积项然后,乘以概率除以体积,我们能得到的就是真正在距离,原子核r处找到电子的概率。
So, basically what we're saying is if we take any shell that's at some distance away from the nucleus, we can think about what the probability is of finding an electron at that radius, and that's the definition we gave to the radial probability distribution.
本质上我们说的就是,如果我们在距离原子核,某处取一个壳层,我们可以考虑在这个半径处,发现电子的概率,这就是我们给出的,径向概率密度的定义。
But there's also a way to get rid of the volume part and actually talk about the probability of finding an electron at some certain area within the atom, and this is what we do using radial probability distribution graphs.
除去体积部分,来讨论,在某些区域内,发现一个原子的概率,我们可以,用,径向概率分布图,它是。
So, if we say that in this entire plane we have zero probability of finding a p electron anywhere in the plane, the plane goes directly through the nucleus in every case but a p orbital, so what we can also say is that there is zero probability of finding a p electron at the nucleus.
而只要是p轨道,这个平面都直接,穿过原子核,那么我们,可以说在原子核上,找到一个p电子的概率为零。
r And what that is the probability of finding an electron in some shell where we define the thickness as d r, some distance, r, from the nucleus.
在某个位置为,厚度为dr的壳层内,找到原子,的概率,我们来考虑下我们这里所说的。
where the probability of actually finding an electron there mp is going to be your maximum probability.
电子的概率,达到最大值,我们把它标记成r下标。
So what we can say is look at each of these separately, so if we start with looking at the 2 p z orbital, the highest probability of finding an electron in the 2 p z orbital, is going to be along this z-axis.
我们可以来分别看看这些图,首先来看看2pz轨道,在2pz轨道里,找到电子的最大概率,是沿着z轴。
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