The partial pressure of the water, of gaseous water above that equilibrium of ice and water is not one bar, it's much less.

哪里错了吗？,问题在于,冰水混合物上方的,大气中水蒸气的分压，不是一个大气压。

麻省理工公开课 - 热力学与动力学课程节选

If I place my container of gas on the table here, and I come back an hour later, the pressure needs to be the same when I come back Otherwise it's not equilibrium.

如果我把装气体的容器放在桌子上，一小时以后我再回来时,气体的压强应该是不变的,否则它就不是平衡的。

麻省理工公开课 - 热力学与动力学课程节选

If I've got a gas in a container, the pressure of the gas has to be the same everywhere in the container, otherwise it's not equilibrium.

如果把气体装进容器里，容器内各处气体的压强,应该是一样的，否则它就不是平衡的。

麻省理工公开课 - 热力学与动力学课程节选

So it's going to shoot up until the internal pressure and the external pressure are in equilibrium.

活塞将上,移直到内外,压强达到平衡。

麻省理工公开课 - 热力学与动力学课程节选

There's our condition for equilibrium at constant temperature and pressure.

这就是我们在,恒定温度和压强下的平衡条件。

麻省理工公开课 - 热力学与动力学课程节选

It's reversible, that means that p external, equals p. I'm doing it very slowly so that I'm always in equilibrium between the external pressure and the internal pressure so I can go back and forth.

我都可以不损失能量，而把过程逆向进行,整个过程中的,每一步都保持平衡,现在我们来分别。

麻省理工公开课 - 热力学与动力学课程节选

OK, we're going to do this reversibly, which means we're going to slowly change the external pressure very, very slightly at a time, so that at every point we're basically in equilibrium, p2/ until the pressure reaches a new smaller pressure p2.

整个过程保持可逆，外界压强,变化得很慢，每一个瞬间,都保持平衡，直到压强减小到末态值。

麻省理工公开课 - 热力学与动力学课程节选

And the triple point of water is 16K that temperature and pressure - there's a unique temperature and pressure where water exists in equilibrium between the liquid phase, the vapor phase, and the solid phase.

与水的三相点,我们定义它为273。,水的三相点,是一个特定的温度和压强,可以使水的液态，气态和固态三相共同达到平衡，三相点是液态。

麻省理工公开课 - 热力学与动力学课程节选

If I look at different points in my container during that path, I'm going to have to use a different value of pressure or different value of temperature That's not an equilibrium state, and that process turns out then to be an irreversible process.

如果我要研究在路径中容器里的,不同的点，我就得在容器里不同的点上使用,不同的压强值,或不同的温度值,实际上这不是个平衡态，这个过程是,不可逆过程。

麻省理工公开课 - 热力学与动力学课程节选

pV Also A plus pV and G is minimized at equilibrium with constant temperature and pressure.

同时等于亥姆赫兹自由能A加上,同时在恒定的温度和压强下。

麻省理工公开课 - 热力学与动力学课程节选

p1 I said let's do this slowly enough that this p1 is in equilibrium with this p1, but not so slowly that this pressure is equivalent to that pressure.

我曾说过我们足够慢地使这边的1,与这边的p1平衡，但是没有慢到,这里的压强等于这里的压强。

麻省理工公开课 - 热力学与动力学课程节选