So let's assume that epsilon prime is greater than epsilon.
假设ε’,比ε大。
epsilon I gave it here a different epsilon, and you'll note, we get different answers.
我换个不同的,你可以看到我们得到的结果还是不同的。
And we can simplify this expression as saying negative e squared over 4 pi, epsilon nought r squared. Epsilon nought is a constant, it's something you might see in physics as well.
也会遇到它,在这里,你可以就把它,理解为一个转换系数,我们需要做的。
And that factor is 4 pi times epsilon zero.
这个常数是4乘π再乘ε
w we have the environment doing work on the system OK, now we've assumed that epsilon prime is greater than epsilon.
大于零,that,is,in,this,one,在这里环境对系统做功,好,现在我们假设,ε’比ε大。
q1*q2/ That's simply q1, q2 over 4 pi epsilon zero R.
那只是简单的。
And now the force, in its most general term / is q1q2 over 4 pi epsilon zero, which is the conversion factor r squared.
库仑力的最基本形式,就是,其中r是一个变量。
Epsilon zero is the permittivity of vacuum.
0是真空中的介电常数。
e The charge on the anion times minus e, so there is the minus e squared, 0R0 and divided by 4 pi epsilon zero r naught, because now I am evaluating this function at r naught, one minus one over n where n is the Born exponent.
阴离子的电荷乘以,因此会有-e的频繁,除以4πε,因为现在我用r圈评估这个函数,1-1/n,n是波恩指数。
I know the energy in this first pair would equal -e^2 That is just going to equal minus e squared over 4 pi epsilon zero r naught.
我们明白第一对的能量将会等于,等于,/4πε0,R圈。
What we need to do is get rid of the Coulomb tag that we have - that's how we measure our electron charges - charge, and so we use this epsilon nought quite often, this permativity constant of a vacuum to make that conversion.
怎么量度电子电荷,所以我们会经常用到,这个epsilon,nought记号,这是真空中的介电常数,我们还要指出,这个介电常数。
That's 4 pi epsilon zero 3 r naught and so on and so on.
也就是,4πε0,3R圈,以此类推。
And we wrote something that looks, the energy is equal to minus the Madelung constant times Avogadro's number, 0R0 q1 q2 over 4 pi epsilon zero R zero.
我们写下了,晶格能等于负的马德隆常数,乘以阿伏伽德罗常数,乘以q1q2除以4πε
In addition to that, we have that epsilon nought value, remember that's the permittivity constant in a vacuum, and basically that is what we use as a conversion factor to get from units. We don't want namely coulombs to units, we want that will allow us to cancel out in this equation.
这是电子的电荷,此外,我们有epsilon零,记住这是真空的介电常数,这是我们用来转换单位的转换常数,我们不想用库伦单位,我们希望这个可以在方程中约去它。
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