When a light particle,or photon, hits an electron, the electron jumps to a higher energy state.

VOA: special.2010.09.01

But it is interesting. Let's just, for an order of magnitude say what happens for ground state electron in atomic hydrogen?

但行星模型其实挺有趣的，按照重要的先后顺序，我们来猜想一下,氢原子中的基态电子会发生些什么？

麻省理工公开课 - 固态化学导论课程节选

In other words, just want to know where the electron is somewhere within the shell radius of the ground state of atomic hydrogen anywhere.

换言之，我只是想知道,电子在哪,可以在氢原子基态下的半径,里面的任何地方。

麻省理工公开课 - 固态化学导论课程节选

We also need to follow Hund's rule, this is that a single electron enters each state before it enters a second state.

我们也需要遵从洪德规则，这是一个电子在进入第二个态之前,要进入每一个态。

麻省理工公开课 - 化学原理课程节选

Now, if this incident energy is great enough it will take an electron out of the ground state and promote it.

现在，如果入射能足够的话,它会将一个电子从基态中释放出来,并且加速它。

麻省理工公开课 - 固态化学导论课程节选

So if we think about, for example, this red line here, which energy state or which principle quantum number do you think that our electron started in?

我们来看看，比如这里的这个红线，它是从主量子数,等于多少的能级发出的？

麻省理工公开课 - 化学原理课程节选

It is the value of the radius of the ground state electron orbit in atomic hydrogen.

它就代表氢原子基态电子,的轨道半径。

麻省理工公开课 - 固态化学导论课程节选

So again, what we're saying here is that it is most likely in the 3 s orbital that we would find the electron 11 and 1/2 times further away from the nucleus than we would in a around state hydrogen atom.

同样我们,这里说的是,氢原子３ｓ轨道中,最可能找到电子的地方,是基态的１１．５倍。

麻省理工公开课 - 化学原理课程节选

What is the binding energy of the ground state electron in hydrogen?

氢在基态的情况下,它的电子结合能是多少？

麻省理工公开课 - 固态化学导论课程节选

This intuitively should make a lot of sense, because we know we're trying to minimize electron repulsions to keep things in as low an energy state as possible, so it makes sense that we would put one electron in each orbital first before we double up in any orbital.

这个直观上讲得通，因为我们知道尝试去最小化电子排斥力,从而尽可能的保持处于一个较低的能态,所以它讲得通,在我们在同一个轨道放入两个电子之前,我们首先把电子放入每一个轨道。

麻省理工公开课 - 化学原理课程节选

So, for example, we could talk about the n equals 2 state, so that's this state here, and it's also what we could call the first excited state. So we have the ground state, and if we excite an electron into the next closest state, we're at the first excited state, or the n equals 2 state.

例如，我们可以考虑n等于2的状态，它在这里，它也被称作是第一激发态,我们有基态，如果我们把一个电子,激发到它最近邻的态,那就是第一激发态，或者n等于2的态。

麻省理工公开课 - 化学原理课程节选

So, if, for example, we were looking at a hydrogen atom in the case where we have the n equals 1 state, so the electron is in that ground state, the ionization energy, it makes sense, is going to be the difference between the ground state and the energy it takes to be a free electron.

电离氢原子所需要的能量,如果我们看n等于1的情况,电子在基态，那电离能，很合理的就是基态,和自由电子态的能量差。

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