SdT This has minus T dS minus S dT, but the dT part is zero because we're at constant temperature.

这一项包含负的Tds和，但是dT的部分等于零,因为温度为常数。

麻省理工公开课 - 热力学与动力学课程节选

v du/dV under constant temperature. du/dT v under constant volume. You use the Joule expansion to find these quantities.

像偏u偏v，恒温下的偏u偏,恒容下的偏u偏,你们知道怎么运用焦耳定律。

麻省理工公开课 - 热力学与动力学课程节选

What is dH/dT as a function, keeping pressure constant, what is dH/dp, keeping temperature constant?

恒定时偏H偏T是什么,温度恒定时的偏H偏p又是什么呢？,好的，让我们解决第一个问题？

麻省理工公开课 - 热力学与动力学课程节选

So we already know that. So now we can write CpdT or differential dH as Cp dT plus dH/dp, pdp constant temperature, dp.

我们已经知道了这个，所以我们现在,可以写出H的微分式：dH等于，加上恒温时的偏H偏。

麻省理工公开课 - 热力学与动力学课程节选

Over here, we have dq=Cp dT, the heat, the proportionality between heat - and temperature rise is given by this, the constant pressure heat capacity.

这里我有dq=CpdT，这是热量，这是联系热量,和温度变化的系数，恒压热容。

麻省理工公开课 - 热力学与动力学课程节选

T Remember, we're trying to get delta H, p we're trying to get dH/dT constant pressure and dH/dp constant temperature. OK, these are the two things were trying to get here.

想要得到在恒压状态下的偏H偏，和在恒温状态下的偏H偏,好的，这是两个我们，在这里想要得到的东西。

麻省理工公开课 - 热力学与动力学课程节选

So if you had a high temperature, this a small compared to b. If you're negative which means that dT/dp at constant H is less than zero.

高于反转温度，这一项相比于b很小,意味着H恒定时,偏T偏p小于零。

麻省理工公开课 - 热力学与动力学课程节选

du/dT constant pressure is the direct derivative with respect to temperature here, which is sitting by itself under constant volume keeping this constant but there is temperature sitting right here too.

偏U偏T，p恒定是对,温度的直接微分，而它本身对体积不变,保持它不变，但是这里也有一个温度,这就是偏U偏V，T恒定。

麻省理工公开课 - 热力学与动力学课程节选