In other words, the order of taking the derivatives with respect to pressure and temperature doesn't matter And what this will show is that dS/dp dS/dp at constant temperature, here we saw how entropy varies with volume, this is going to show us how it varies with pressure.
换句话说,对温度和压强的求导顺序无关紧要,结果会表明,恒定温度下的,对应我们上面看到的,熵如何随着体积变化,这个式子告诉我们,熵如何随着压强变化。
Normally I couldn't do that Vdp because this term would have p dV plus V dp, but we've specified the pressure is constant, so the dp part is zero.
一般情况下我不能这么写,因为这一项会包含pdV和,但是我们已经假定压强为常数,所以包含dp的部分等于零。
What is dH/dT as a function, keeping pressure constant, what is dH/dp, keeping temperature constant?
恒定时偏H偏T是什么,温度恒定时的偏H偏p又是什么呢?,好的,让我们解决第一个问题?
T Remember, we're trying to get delta H, p we're trying to get dH/dT constant pressure and dH/dp constant temperature. OK, these are the two things were trying to get here.
想要得到在恒压状态下的偏H偏,和在恒温状态下的偏H偏,好的,这是两个我们,在这里想要得到的东西。
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