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with fresh shucked oysters. "We do about P&J is a part of Louisiana's the largest in the U.S.
VOA: standard.2010.05.08
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And these shapes of p orbitals probably do look familiar to you, most of you, I'm sure, have seen some sort of picture of p orbitals before.
这些ｐ轨道的形状你们可以能已经很熟悉了，我相信大部分人，都看过ｐ轨道的图片。
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Remember, we don't do a one-to-one correlation, because p x and p y are some linear combination of the m plus 1 and m minus 1 orbital.
记住，我们不需要把它们一一对应，因为ｐｘ和ｐｙ轨道是,ｍ等于正负１轨道的线性组合。
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If I do the following, and I say, I'm going to assign p 1 to be p 2.
现在我要去做一些改动，这是为了让大家,更好的理解这一点。
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They don't care that there are other atoms and molecules around. So that's basically what you do when you take p goes to zero.
这正是当压强无限小时,气体的行为,气体的体积无限大。
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So the proposal that death is a matter of permanent cessation of P-functioning versus temporary, that doesn't seem like it's going to do the trick.
所以说死亡只永久地,停止人格功能性的这个说法，也不是正确的。
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He said he could do it if we could arrange to meet after 3:00 p.m., so I'm going to--on a Monday or a Wednesday, perhaps at 3:00 p.m. or later.
他说下午三点以后也许可以,所以我想安排在周一或周三,下午三点或更晚
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What do these look like? These are p-orbitals.
这看起来像什么，是p轨道。
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We did it for the s orbitals, we can also do it for the p, we can do it for the d.
我们对ｓ轨道这样做了，我们也可以对ｐ轨道这样做，对ｄ轨道这样做。
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Let's look now at a p orbital, so how many total nodes do we have here?
让我们来看看ｐ轨道，它有多少个节点呢？
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So let's do c p 1 dot y, c p 2 dot y.
这不太好因为，两个地方的值都是一样的，对不对？
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So for example, if we think about fluorine, 1 s 2 2 s 2 2 p 5 that has an electron configuration of 1 s 2, 2 s 2, 2 p 5, so all we would need to do is add one more electron to get the same configuration as for neon.
比如，如果我们考虑氟原子的话，它的电子排布是，因此我们所需要做的就是给它加上一个电子,使得它与氖原子的电子排布相同。
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All right. So let's look now at the case where we do have 2 p z orbitals that we're talking about.
好的，让我们现在看一个,需要2pz轨道的例子。
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If I'm not P-functioning, do we have to then say I'm dead?
如果我没有人格功能性，可以说我死了吗？
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Normally I couldn't do that Vdp because this term would have p dV plus V dp, but we've specified the pressure is constant, so the dp part is zero.
一般情况下我不能这么写,因为这一项会包含pdV和，但是我们已经假定压强为常数，所以包含dp的部分等于零。
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We want to do that because we have too many variables here. We've already got dV p we'll get rid of p as an additional variable and replace it with V which is already in here.
我们之所以要那么做,是因为这儿有太多变量了,我们已经有了dV，我们要把,作为额外的变量消去，用已存在的V代换它。
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So it might look like here, if you don't understand about p orbitals, which I know all you do, but if someone else was just looking and seeing, it kind of looks like there's two bonds here.
这里看起来有点像，如果你们不知道p轨道的话，我知道你们都知道，但如果另外有个人看到这个，这看起来有点像两个键。
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I'm sure you're thinking well, what do we do in the case of p orbitals, and, in fact, we can do the same thing.
我相信你们也会想，如果有p轨道会怎样，实际上，我们也可以一样做。
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And the significant difference between s orbitals and p orbitals that comes from the fact that we do have angular momentum here in these p orbitals, is that p orbital wave functions do, in fact, have theta and phi dependence.
轨道和ｐ轨道的,不同之处在于,在ｐ轨道，波函数，随theta和phi变化。
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Keep in mind we do have this p orbital here and it's coming right out at us. And this p orbital is here, but it's empty, it doesn't have any electrons in it, that's why we don't have to worry about it in terms of getting our electrons as far away from each other as possible.
他们程120度角互相远离,这样它们离得最远，记住我们这里确实有个p轨道，它朝向我们，这里有个p轨道，但它是空的,里面没有电子,这就是为什么我们在考虑。
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Why do we just see one for all the p's?
为什么我们只看到了一条只是关于，p，的？
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Let's do it in fact. OK.
好，那么p现在。
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So now we're putting 2 electrons into the same p orbital, that's not a problem, we can do it, it's not a huge energy cost to do that.
现在我们在同一个，p，轨道上放了两个电子，这没问题，我们可以这样做，这样不会亏损太多能量。
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Now let's do the following.
首先让p作为一个笛卡尔点。
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So if we take our carbon atom here, which has two electrons in the 2 s orbital, and we promote one of these electrons into a 2 p orbital, what we see now is that yes, we do, we have four unpaired electrons.
这是碳原子，2s轨道里有两个电子，我们把一个电子激发到2p轨道里，我们看到现在，是的，我们有4个未配对电子。
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