Now we can use it to derive differential relations for all of the thermodynamics quantities.
现在我们可以利用他们,推导所有热力学量的微分关系。
So this isn't the most useful form that we can have, but what we'll see shortly is that from this, we can then derive further criteria for essentially any set of variables or any set of external constraints, like constant temperature or pressure or volume and so forth that we might set.
所以这不是我们所能得到的最有用的形式,但是我们会很快看到,我们能够进一步推导出包含任意变量,或者任意约束的自发过程判断标准,比如说恒定的温度,压强,体积或者其他我们能够给出的约束。
So, essentially when we're talking about these equations up here, all we're doing is talking about the regular Rydberg formulas, but instead we could go back and re-derive the equation for any one electron atom, which would just mean that we put that z squared term in the front.
所以本质上,当我们讨论,这些问题时,我们说的是常规的,Rydberg公式,但对任何其他单电子原子,我们不用,从头再推到,而是仅仅把,z平方项放在前面。
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