Delta u, delta H, familiar state functions, q w changes in their values, q, w, heat and work.
U,△H,很熟悉的态函数,它们的值在变化;
Delta v is positive in this direction here, the work is negative. So work on the system is positive. Work done by the system is negative.
功是负的,总而言之,外界对系统做功的符号为正。
So if delta v is negative, in this case delta v is negative, OK, delta v is negative, pressure is a positive number, negative times negative is positive, work is greater than zero.
也就是当活塞,压缩气体的时候,做的功是正的,按照这一规定,我们需要在这里,加上一个负号,这是习惯规定。
So delta u is just equal to the work but we also know what happens T2 because the temperature is changing from T1 to T2.
所以Δu等于输出的功,但我们也知道它会发生,同时我们知道温度从T1变到。
q Work is zero. Delta u is w plus q, work plus heat. This is zero, this isn't.
功是零,△U是w加,功加上热量,这个是零。
It makes sense, right, because you know we got less work out and delta u is the same right, so it must be that less heat got transferred.
这是显而易见的,因为输出的功更少,且Δu相等,所以需要的热量更少。
U And then if we can also determine delta u, then we know this, we know delta u is q plus w w, then we can determine work as well, right?
然后,如果我们也能定出△,然后我们知道这个,我们知道△U等于q加?
V Minus p2, V2. Minus p delta V. So the total work is the work from the left hand side plus the work on the right hand side, p1 V1- p2 V2 which is p1 V1 minus p2 V2.
负p2V2【w=-p2v2】,即负pΔ,所以全部的功就是,左边的功加上右边的功,等于。
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